Sodium metabisulfite

CAS Number
7681-57-4
EC Number
231-673-0
Chemical Formula
H2O5S2.2Na
Molecular Weight
190.11 g/mol
E Number
E223
Abbreviation
SMBS

Description

Sodium metabisulfite (CAS 7681-57-4), also known as sodium pyrosulfite and sold under the abbreviation SMBS, is an inorganic sulfite salt used across food, industrial, and water treatment sectors. It serves as a preservative, antioxidant, and reducing agent. As E223, it is a regulated food additive recognized in major international markets. Its ability to release sulfur dioxide under controlled conditions underpins its function across multiple industries and specialized chemical processes.

In food and beverage production, E223 prevents oxidative browning and microbial spoilage in dried fruits, wines, seafood, and fruit juices. This ensures product longevity and maintains the aesthetic quality of processed goods. Water treatment plants use SMBS to neutralize residual chlorine in municipal and industrial effluent streams before discharge or further processing. This step is critical for environmental safety and protecting downstream equipment.

Textile and leather processors apply it as a bleaching and reducing agent in dye stripping and chrome tanning operations. It provides consistent results in heavy industrial manufacturing environments requiring high-purity chemical inputs. In pharmaceutical manufacturing, it functions as an antioxidant stabilizer in injectable formulations and oral solutions. This is essential where oxygen-sensitive active ingredients require protection to maintain their therapeutic efficacy.

Sodium metabisulfite is supplied as a white to off-white crystalline powder or fine granules. Standard commercial grades include food-grade (FCC-compliant), USP/BP pharmaceutical grade, and technical grade for industrial applications. Bulk supply is available in 25 kg bags, with food and pharma grades accompanied by full compliance documentation. Our logistics network ensures reliable delivery for large-scale manufacturing and chemical processing facilities worldwide.

Other Names (Synonyms)

sodium pyrosulfite|sodium metabisulphite|disodium pyrosulfite|Sodium disulfite|Natrii disulfis|Campden Tablets|Disodium metabisulfite|Natrium pyrosulfit|SMBS|E223

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 150 °C (decomp)
Density 1.4 g/cm³
Appearance Sodium metabisulfite is a white crystalline powder. Sulfur dioxide odor. It may be considered the anhydride of 2 molecules of sodium disulfite.
Color White to slightly yellow
Odor Sulphorous
Form Powder/Solid
Water Solubility 540 g/L (20 ºC)
Refractive Index 1.474
pH 3.5-5 (50g/l, H2O, 20℃)

Documentation

Safety & Handling Learn More

Danger
GHS05· Corrosive GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H302 Harmful if swallowed
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H320 Causes eye irritation

Precautionary Statements

P233 Keep container tightly closed.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Trade & Regulatory

HS Code 28323010
Storage Class 13 - Non Combustible Solids
WGK (Germany) 1
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