Sodium bisulfate

CAS Number
7681-38-1
EC Number
231-665-7
Abbreviation
NaHSO4

What is Sodium bisulfate?

Sodium bisulfate (CAS 7681-38-1), also sold as sodium acid sulfate, is a dry acid used to lower pH and adjust acidity.

Where is Sodium bisulfate used?

  • Food processing: acidulant and pH regulator in meat products and potato-based foods
  • Water treatment: reduces alkalinity and adjusts pH in pools, municipal systems and industrial effluent streams
  • Metal finishing and mining: pickles metal surfaces and dissolves oxide layers
  • Cleaning formulations: acidic backbone for descalers, toilet bowl cleaners and hard surface products
  • It serves as a solid replacement for liquid mineral acids in handling processes.
  • Jewelry making: used as a primary ingredient to clean surfaces.
  • Food additive in yeast-raised cake mixes as a leavening agent.

Good to know: Its solid form is a practical alternative to sulfuric acid where liquid acids present handling or logistics challenges. Granular form is preferred for bulk handling, reducing dust exposure during dosing.

Formulation notes

  • Reacts strongly with strong bases and strong oxidizing agents.
  • Safer and easier to use than hydrochloric (muriatic) acid.

Typical specification

  • Food grade has actives content of 92-100%.
  • Supplied in crystal, granule and powder forms.
  • Commonly available in both anhydrous and monohydrate forms.
  • Corresponds to at least 37.6% equivalent H2SO4 by titration with NaOH.

Regulatory status

  • Monohydrate is classified as causing serious eye damage/eye irritation Category 1 with hazard statement H318.
  • Food grade is listed on the Safer Chemical Ingredient List.
  • Approved by AAFCO as a general-purpose feed additive, including for complementary pet food.

Storage, packaging and handling

  • Typically supplied in bulk tankers, 200-liter drums, and 1,000-liter IBCs.
  • During storage, protect from moisture.
  • Store in a dry environment, away from moisture, with suitable ventilation conditions.

Frequently asked questions about Sodium bisulfate

In which textile processes can sodium bisulfate be used?
It can be used as a pH regulator in dyeing and finishing processes in the textile sector.

Technical content is compiled and updated by the SoleChem product team from public technical sources; the certificate of analysis (COA) governs product-specific specifications.

Other Names (Synonyms)

sodium hydrogensulfate|sodium acid sulfate|monosodium sulfate|Nitre cake|sodium bisulphate|Sodium hydrogensulphate|Bisulfate of soda|Sodium hydrosulfate|NaHSO4

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What are the physical properties of Sodium bisulfate?

Melting Point 58 °C
Density 2.1
Appearance off-white granules, crystals or powder
Color White to light yellow
Form Granules
Water Solubility soluble in 2 parts H2O, 1 part boiling H2O; decomposes in alcohol to sodium sulfate and H2SO4 [MER06]

How is Sodium bisulfate classified and handled safely? Learn More

Danger
GHS05· Corrosive GHS07· Irritant

Hazard Statements

H318 Causes serious eye damage
H319 Causes serious eye irritation

Precautionary Statements

P280 Wear protective gloves/protective clothing/eye protection/face protection.
P317 Get emergency medical help.
P264+P265 Wash … thoroughly after handling.
P337+P317 If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P305+P354+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Which trade and regulatory codes apply to Sodium bisulfate?

HS Code 28331900
Storage Class 11 - Combustible Solids
WGK (Germany) 1
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