Sulfur dioxide

CAS Number
7446-09-5
EC Number
231-195-2
FEMA Number
FEMA 3039
Abbreviation
SO2

What is Sulfur dioxide?

Sulfur dioxide (CAS 7446-09-5), commonly referenced as SO2 or E220, is an inorganic gas used in food processing, industrial manufacturing, and water treatment.

Where is Sulfur dioxide used?

  • Food and beverage: preservative, antioxidant, and reducing agent in wines, dried fruits, and fruit juices
  • Pulp and paper: bleaches cellulose fibers and neutralizes excess chlorine in effluent streams
  • Mining and hydrometallurgy: reduces hexavalent chromium and precipitates metals from process liquors during ore refining
  • Water treatment facilities apply it for dechlorination of potable and wastewater streams.
  • Chemical intermediate in the production of sulfuric acid, sulfites, potassium and sodium hydrosulfites, and thiosulfates.
  • Used in the sulfonation of oils.
  • Used in oil refining, representing 4% of its use.

Good to know: Its dual role in microbial control and oxidation prevention makes it a procurement staple across multiple regulated industries.

Typical specification

  • Non-volatile residue is not more than 0.05%.

Regulatory status

  • Classified under CLP as a gas under pressure that may explode when heated, with hazard statement H280.
  • Classified under CLP as causing severe skin burns and serious eye damage, with hazard statement H314.
  • Classified under CLP as a refrigerated gas that can cause cryogenic burns or injury, with hazard statement H281.
  • If sulfur dioxide or sulfite salts are present in foods, they must be labeled regardless of the type of use at a concentration of 10 mg/kg (or 10 mg/l) or more.

Storage, packaging and handling

  • Contact between liquid sulfur dioxide and water may cause vigorous boiling and extremely rapid vaporization, with explosion possible if the water is hot.

Technical content is compiled and updated by the SoleChem product team from public technical sources; the certificate of analysis (COA) governs product-specific specifications.

Other Names (Synonyms)

Sulphur dioxide , sulfur dioxide|sulphur dioxide|sulfurous oxide|sulfurous anhydride|sulfurous acid anhydride|sulfur oxide|R-764|SO2|E220

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What are the physical properties of Sulfur dioxide?

Melting Point -75.5 °C
Boiling Point -10.05 °C
Density 2.811 x 10<sup>-3</sup> g/cm³
Appearance Sulfur dioxide is a noncombustible colorless gas at ambient temperatures with a characteristic, strong, suffocating odor. The Odor Threshold is 1.1ppm. Shipped as a liquefied compressed gas.
Color colorless
Odor Pungent odor detectable at 0.3 to 5 ppm
Form colorless gas
Water Solubility %H2O: 17.7 (0°C), 11.9 (15°C), 8.5 (25°C), 6.4 (35°C); % other solvents: 25, alcohol; 32, methanol [MER06]
Vapor Pressure 1779 mm Hg ( 21 °C)

How is Sulfur dioxide classified and handled safely? Learn More

Danger
GHS04· Compressed Gas GHS05· Corrosive GHS06· Toxic GHS08· Health Hazard GHS07· Irritant

Hazard Statements

H280 Contains gas under pressure; may explode if heated
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H319 Causes serious eye irritation

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.

Which trade and regulatory codes apply to Sulfur dioxide?

UN Number 2037
ADR Class 2.3
Storage Class 2A - Gases
WGK (Germany) 1
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