Selenium dioxide

CAS Number
7446-08-4
EC Number
231-194-7
Chemical Formula
O2Se
Molecular Weight
110.97 g/mol
Abbreviation
SeO2

Description

Selenium dioxide (CAS 7446-08-4), also known as selenious anhydride, is an inorganic oxidizing agent used primarily as a catalyst and reagent in chemical synthesis and industrial refining. SeO2 enables selective oxidation reactions that are difficult to achieve with conventional oxidants, making it a targeted choice for specialty chemical production and advanced manufacturing.

In organic synthesis, it is the reagent of choice for allylic and benzylic oxidations, converting methylene groups to carbonyl compounds in pharmaceutical and fine chemical intermediates. The electronics industry relies on it as a component in glass and ceramic formulations where controlled selenium incorporation modifies optical and electrical properties for high-tech use.

In metallurgy and mining, it functions as a refining agent for copper and other non-ferrous metals, removing impurities during electrorefining processes to ensure high metal purity. It also serves as a precursor in the production of other selenium compounds used across pigment and catalyst manufacturing, supporting a wide range of industrial chemical applications.

The product is supplied as a white crystalline powder. Technical and reagent grades are the standard market offerings, with purity levels typically ranging from 99% upward for use. Packaging is available in small quantities for research use through to bulk quantities for industrial procurement, with handling requirements reflecting its oxidizing classification.

Other Names (Synonyms)

Selenous anhydride|Selenium(IV) oxide|Selenious anhydride|Selenium oxide (SeO2)|Selenium dioxide dimer|Selenous acid anhydride|Selenium(IV) dioxide (1:2)|Selenium oxide (Se2O4)|SeO2

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 340 °C
Boiling Point 684.9 °C(lit.)
Density 3.954 g/cm³ @ Temp: 15 °C
Flash Point 315°C
Appearance Selenium dioxide is white to slightly reddish crystalline solid or yellow liquid which forms a yellowgreen vapor. It has a sour and pungent odor. Odor threshold in air50.0002 milligram per cubic meter.
Color white
Form powder
Water Solubility 38.4 g/100 mL (14 ºC)
Vapor Pressure 1 mm Hg ( 157 °C)
Refractive Index nD20 <1.76
pH 2 (10g/l, H2O, 20℃)

Documentation

Safety & Handling Learn More

Danger
GHS05· Corrosive GHS06· Toxic GHS08· Health Hazard GHS09· Environmental Hazard GHS07· Irritant

Hazard Statements

H300 Fatal if swallowed
H301 Toxic if swallowed
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.

Trade & Regulatory

HS Code 28112900
UN Number 3440
ADR Class 6.1
Packing Group III
Storage Class 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
WGK (Germany) 2
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