Thiourea dioxide

CAS Number
1758-73-2
EC Number
217-168-4
Abbreviation
TDO

What is Thiourea dioxide?

Thiourea dioxide (CAS 1758-73-2), also known as formamidinesulfinic acid and abbreviated TDO, is a reductive bleaching and reducing agent.

Where is Thiourea dioxide used?

  • Textile processing: reductive clearing after dyeing with disperse dyes on polyester, removing unfixed surface dye to improve wash fastness and colour brightness
  • Pulp and paper: bleaching mechanical and chemical pulps where brightness reversion must be minimised
  • Leather processing: uniform whitening of hides prior to dyeing for consistent colour uptake
  • Water treatment and industrial effluent: reducing agent that neutralises residual oxidants such as chlorine and chromate compounds
  • Under alkaline and elevated-temperature conditions it acts as a controlled source of reducing power, enabling selective bleaching and colour stripping without the aggressive fibre damage of oxidative systems.

Commercial specifications

  • Technical grade for industrial processing, purity typically 98% or higher
  • 25 kg bags or drums for bulk industrial procurement

Other Names (Synonyms)

Thiourea S,S-dioxide|Formamidinesulfinic acid|Formamidine sulfinate|Aminoiminomethanesulfinic acid|Manofast|42BWR07L73|Methanesulfinic acid, 1-amino-1-imino-|TDO

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What are the physical properties of Thiourea dioxide?

Melting Point 142-143 °C (decomp)
Boiling Point 355.3±25.0 °C(Predicted)
Density 1.68
Appearance white crystalline powder
Color White
Form Crystalline Powder
Water Solubility 30 g/L (20 ºC)
Vapor Pressure 0Pa at 25℃
Refractive Index 1.6550 (estimate)
pH 4 (10g/l, H2O, 20℃)
Log P -3.37 at 25℃

How is Thiourea dioxide classified and handled safely? Learn More

Danger
GHS02· Flammable GHS05· Corrosive GHS07· Irritant GHS08· Health Hazard GHS06· Toxic

Hazard Statements

H251 Self-heating; may catch fire
H252 Self-heating in large quantities; may catch fire
H302 Harmful if swallowed
H315 Causes skin irritation

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P235 Keep cool.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

Which trade and regulatory codes apply to Thiourea dioxide?

HS Code 29309070
UN Number 3341
ADR Class 4.2
Packing Group II
Storage Class 4.2 - Pyrophoric and self-heating hazardous materials
WGK (Germany) 1
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