Tetrabromophthalic anhydride

CAS Number
632-79-1
EC Number
211-185-4
Chemical Formula
C8Br4O3
Molecular Weight
463.70 g/mol
Abbreviation
TBPA

Description

Tetrabromophthalic anhydride (CAS 632-79-1), commonly abbreviated as TBPA and marketed under the trade name FireMaster PHT 4, is a reactive and additive bromine-based flame retardant used across plastics, electronics, and textile manufacturing. Its high bromine content makes it effective at meeting stringent flammability standards in demanding end-use applications. In electronics, TBPA is incorporated into epoxy resins and printed circuit board laminates.

This allows manufacturers to achieve UL 94 flame retardancy ratings required by component manufacturers. Polyester and polyurethane foam producers use it as a reactive intermediate, chemically bonding it into the polymer backbone. This process helps to reduce migration and improve durability of flame retardant performance. Textile and upholstery back-coating formulations use TBPA-derived diols to meet fire safety regulations for commercial furnishings.

It is also utilized for transportation seating. In rigid and flexible polymer systems, it functions as both a processing additive and a reactive monomer, giving formulators flexibility in how flame retardancy is built. TBPA is supplied as an off-white to pale yellow crystalline powder. It is available in technical grade, with purity specifications typically at 98% or higher depending on specific industrial application requirements.

Packaging options commonly include 25 kg bags and bulk quantities suited to industrial procurement volumes. This ensures a reliable supply chain for large-scale manufacturing operations across various global sectors.

Other Names (Synonyms)

FireMaster PHT 4|Tetrabromophthalic acid anhydride|Phthalic anhydride, tetrabromo-|1,3-Isobenzofurandione, 4,5,6,7-tetrabromo-|Saytex RB 49|PHT 4|4,5,6,7-Tetrabromo-1,3-isobenzofurandione|TBPA

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 279.5-280.5 °C
Boiling Point 540.5±50.0 °C(Predicted)
Density 2.87
Appearance white to light yellow powder
Color White to light yellow
Form Powder
Water Solubility hydrolysis
Vapor Pressure 0.11 mm Hg ( 180 °C)
Refractive Index 1.5000 (estimate)
Log P 2.27 at 40℃

Safety & Handling (Learn More)

Warning
GHS07· Irritant

Hazard Statements

H317 May cause an allergic skin reaction

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P321 Specific treatment (see … on this label).
P501 Dispose of contents/container in accordance with local regulations.
P302+P352 IF ON SKIN: Wash with plenty of water.
P333+P317 Get emergency medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.

Trade & Regulatory

HS Code 29173911
Storage Class 11 - Combustible Solids
WGK (Germany) 2

Documentation

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