Tetrabromophthalic anhydride

CAS Number
632-79-1
EC Number
211-185-4
Abbreviation
TBPA

What is Tetrabromophthalic anhydride?

Tetrabromophthalic anhydride (CAS 632-79-1), commonly abbreviated as TBPA and marketed under the trade name FireMaster PHT 4, is a reactive and additive bromine-based flame retardant.

Where is Tetrabromophthalic anhydride used?

  • Electronics: incorporated into epoxy resins and printed circuit board laminates
  • Polyester and polyurethane foam: reactive intermediate chemically bonding into the polymer backbone
  • Textile and upholstery back-coating: TBPA-derived diols for fire safety regulations in commercial furnishings
  • Transportation seating
  • In rigid and flexible polymer systems it functions as both a processing additive and a reactive monomer.

Good to know: Its high bromine content makes it effective at meeting stringent flammability standards, allowing manufacturers to achieve UL 94 flame retardancy ratings. Reactive bonding into the polymer backbone helps reduce migration and improve durability of flame retardant performance.

Commercial specifications

  • Purity specifications typically 98% or higher depending on specific industrial application requirements
  • Packaging options commonly include 25 kg bags and bulk quantities suited to industrial procurement volumes

Other Names (Synonyms)

FireMaster PHT 4|Tetrabromophthalic acid anhydride|Phthalic anhydride, tetrabromo-|1,3-Isobenzofurandione, 4,5,6,7-tetrabromo-|Saytex RB 49|PHT 4|4,5,6,7-Tetrabromo-1,3-isobenzofurandione|TBPA

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What are the physical properties of Tetrabromophthalic anhydride?

Melting Point 279.5-280.5 °C
Boiling Point 540.5±50.0 °C(Predicted)
Density 2.87
Appearance white to light yellow powder
Color White to light yellow
Form Powder
Water Solubility hydrolysis
Vapor Pressure 0.11 mm Hg ( 180 °C)
Refractive Index 1.5000 (estimate)
Log P 2.27 at 40℃

How is Tetrabromophthalic anhydride classified and handled safely? Learn More

Warning
GHS07· Irritant

Hazard Statements

H317 May cause an allergic skin reaction

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P321 Specific treatment (see … on this label).

Which trade and regulatory codes apply to Tetrabromophthalic anhydride?

HS Code 29173911
Storage Class 11 - Combustible Solids
WGK (Germany) 2
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