Tetrachlorophthalic anhydride

CAS Number
117-08-8
EC Number
204-171-4
Chemical Formula
C8Cl4O3
Molecular Weight
285.9 g/mol
Abbreviation
TCPA

Description

Tetrachlorophthalic anhydride (CAS 117-08-8), commonly abbreviated as TCPA, is a chlorinated cyclic anhydride used as a reactive flame retardant and chemical intermediate across polymer and coating systems. Unlike additive flame retardants, it bonds directly into polymer backbones, delivering durable fire resistance without migration losses. In epoxy resin formulations for printed circuit boards, TCPA acts as a curing agent.

It simultaneously imparts halogenated flame retardancy to the cured matrix. Polyester and alkyd resin producers incorporate it as a monomer to build fire-retardant properties into coatings used in construction panels. Industrial textiles and paper treatment processes use TCPA-derived intermediates to meet flame resistance standards required in packaging and protective fabrics. It also functions as a plasticizer precursor in PVC compounding.

Its chlorine content contributes to both flexibility and reduced flammability in finished profiles and films. Tetrachlorophthalic anhydride is supplied as an off-white to pale yellow crystalline powder for industrial use. Technical grade is the standard commercial specification, with purity levels typically at 98% or higher. Bulk quantities are available in fiber drums or multi-wall bags suited for industrial procurement volumes.

Other Names (Synonyms)

Tetrathal|etrachlorophthalic acid anhydride|4,5,6,7-Tetrachloro-1,3-isobenzofurandione|1,3-Dioxy-4,5,6,7-tetrachloroisobenzofuran|Niagathal|1,3-Isobenzofurandione, 4,5,6,7-tetrachloro-|4,5,6,7-Tetrachloro-2-benzofuran-1,3-dione|Phthalic anhydride, tetrachloro-|TCPA

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 255-256.5 °C
Boiling Point 371 °C
Density 1.49
Flash Point 362°C
Appearance white needle-like crystals or powder
Color White to off-white
Form Flakes
Water Solubility 0.8 mg/L (21 ºC)
Vapor Pressure 0.16 mm Hg ( 145 °C)
Log P 3.2 at 25℃

Documentation

Safety & Handling Learn More

Danger
GHS05· Corrosive GHS08· Health Hazard GHS09· Environmental Hazard GHS07· Irritant

Hazard Statements

H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H320 Causes eye irritation
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled

Precautionary Statements

P233 Keep container tightly closed.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Trade & Regulatory

HS Code 29173990
UN Number 3077
ADR Class 9
Packing Group III
Storage Class 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
WGK (Germany) 2
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