Trimellitic anhydride

CAS Number
552-30-7
EC Number
209-008-0
Chemical Formula
C9H4O5
Molecular Weight
192.12 g/mol
Abbreviation
TMA

Description

Trimellitic anhydride (CAS 552-30-7), commonly abbreviated as TMA, is a reactive aromatic anhydride used as a monomer and curing agent across polymer and coating systems. It introduces carboxylic acid functionality into resin backbones, enabling cross-linking, chain extension, and surface-reactive formulations. In high-performance coatings, TMA is reacted with polyols or amines to produce polyimide and polyester resins that withstand elevated temperatures and chemical exposure. These specialized resins are essential for industrial applications requiring durability.

The plastics industry uses it to manufacture plasticizers, particularly trimellitate esters, for flexible PVC in wire and cable insulation. These materials require low volatility at high operating temperatures to ensure safety and longevity. Adhesive and sealant formulators incorporate TMA as a cross-linking monomer to improve heat resistance and adhesion to metal substrates. This chemical property makes it a vital component in demanding structural bonding applications.

In pigment and dye manufacturing, it acts as an intermediate in the synthesis of reactive dyes and color developers. Its unique structure allows for the creation of stable and vibrant colorants used in various industrial sectors. Trimellitic anhydride is supplied as an off-white to pale yellow crystalline powder or flake. Technical grade is the standard commercial form, with purity typically at 98–99%+ by GC, ensuring consistent performance in chemical synthesis.

Packaging ranges from multi-wall bags to bulk supersacks to meet diverse logistical needs. Storage requirements for moisture-sensitive handling are strictly communicated in product documentation to maintain material integrity.

Other Names (Synonyms)

Trimellitic acid cyclic 1,2-anhydride|Trimellitic acid anhydride|Trimellitic acid 1,2-anhydride|Trimellic acid anhydride|Trimellic acid 1,2-anhydride|Benzene-1,2,4-tricarboxylic-1,2-anhydride|Anhydrotrimellitic acid|Anhydrotrimellic acid|TMA

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 161-163.5 °C
Boiling Point 390 °C
Density 1.54
Flash Point 227 °C
Appearance Trimellitic anhydride is a crystalline solid. It is the anhydride of trimellitic acid (1,2,4-benzenetricarboxylic acid).
Color White to off-white
Form Flakes
Water Solubility DECOMPOSES
Vapor Pressure <0.01 mm Hg ( 20 °C)
Refractive Index 1.4717 (estimate)
pH 2 (21g/l, H2O, 20℃)
Log P 0.06-0.54 at 20℃

Documentation

Safety & Handling Learn More

Danger
GHS05· Corrosive GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H303 May be harmful if swallowed
H316 Causes mild skin irritation
H317 May cause an allergic skin reaction
H318 Causes serious eye damage

Precautionary Statements

P233 Keep container tightly closed.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Trade & Regulatory

HS Code 29173980
Storage Class 11 - Combustible Solids
WGK (Germany) 1
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