Trimellitic anhydride
Description
Trimellitic anhydride (CAS 552-30-7), commonly abbreviated as TMA, is a reactive aromatic anhydride used as a monomer and curing agent across polymer and coating systems. It introduces carboxylic acid functionality into resin backbones, enabling cross-linking, chain extension, and surface-reactive formulations.
In high-performance coatings, TMA is reacted with polyols or amines to produce polyimide and polyester resins that withstand elevated temperatures and chemical exposure. These specialized resins are essential for industrial applications requiring durability.
The plastics industry uses it to manufacture plasticizers, particularly trimellitate esters, for flexible PVC in wire and cable insulation. These materials require low volatility at high operating temperatures to ensure safety and longevity.
Adhesive and sealant formulators incorporate TMA as a cross-linking monomer to improve heat resistance and adhesion to metal substrates. This chemical property makes it a vital component in demanding structural bonding applications.
In pigment and dye manufacturing, it acts as an intermediate in the synthesis of reactive dyes and color developers. Its unique structure allows for the creation of stable and vibrant colorants used in various industrial sectors.
Trimellitic anhydride is supplied as an off-white to pale yellow crystalline powder or flake. Technical grade is the standard commercial form, with purity typically at 98–99%+ by GC, ensuring consistent performance in chemical synthesis.
Packaging ranges from multi-wall bags to bulk supersacks to meet diverse logistical needs. Storage requirements for moisture-sensitive handling are strictly communicated in product documentation to maintain material integrity.
Physical Properties
| Melting Point | 161-163.5 °C |
| Boiling Point | 390 °C |
| Density | 1.54 |
| Flash Point | 227 °C |
| Appearance | Trimellitic anhydride is a crystalline solid. It is the anhydride of trimellitic acid (1,2,4-benzenetricarboxylic acid). |
| Color | White to off-white |
| Form | Flakes |
| Water Solubility | DECOMPOSES |
| Vapor Pressure | <0.01 mm Hg ( 20 °C) |
| Refractive Index | 1.4717 (estimate) |
| pH | 2 (21g/l, H2O, 20℃) |
| Log P | 0.06-0.54 at 20℃ |
Safety & Handling (Learn More)
Trade & Regulatory
| HS Code | 29173980 |
| Storage Class | 11 - Combustible Solids |
| WGK (Germany) | 1 |
Documentation
Other Names
Trimellitic acid cyclic 1,2-anhydride|Trimellitic acid anhydride|Trimellitic acid 1,2-anhydride|Trimellic acid anhydride|Trimellic acid 1,2-anhydride|Benzene-1,2,4-tricarboxylic-1,2-anhydride|Anhydrotrimellitic acid|Anhydrotrimellic acid|TMA
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