Trimethylolpropane

CAS Number
77-99-6
EC Number
201-074-9
Abbreviation
TMP

What is Trimethylolpropane?

Trimethylolpropane (CAS 77-99-6), commonly abbreviated as TMP, is a trifunctional aliphatic alcohol used as a building block in polymer synthesis and resin manufacturing.

Where is Trimethylolpropane used?

  • Coatings: reacts with isocyanates or melamine resins to produce polyurethane and alkyd systems with improved hardness, flexibility, and chemical resistance
  • Adhesives and sealants: builds polyurethane prepolymers where controlled cross-link density affects bond strength and elasticity
  • Plastics: branching agent in polyester and polycarbonate production, influencing molecular weight distribution and mechanical performance
  • Personal care: humectant and stabilizer in emollient systems and film-forming preparations
  • Its three hydroxyl groups enable controlled cross-linking and branching.

Commercial specifications

  • Standard commercial grades include technical and industrial purity levels
  • Typically at 99%+ purity
  • Specialty grades meeting stricter quality specifications for cosmetic and high-performance polymer applications

Other Names (Synonyms)

2-ethyl-2-hydroxymethyl-1,3-propanediol|TMP|1,1,1-TRIS(HYDROXYMETHYL)PROPANE|Ethriol|Etriol|Ettriol|TMP (alcohol)|1,3-Propanediol, 2-ethyl-2-(hydroxymethyl)-

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What are the physical properties of Trimethylolpropane?

Melting Point 58 °C
Boiling Point 160 °C @ Press: 5 Torr
Density 1.176
Flash Point 172 °C
Appearance Colorless, hygroscopic crystals. Soluble in water and alcohol. Combustible.
Color White
Form Flakes
Water Solubility soluble
Vapor Pressure <1 mm Hg ( 20 °C)
Refractive Index 1.4850 (estimate)
pH 6.5 (100g/l, H2O, 20℃)(External MSDS)
Log P -0.975 (est)

How is Trimethylolpropane classified and handled safely? Learn More

Danger
GHS08· Health Hazard

Hazard Statements

H360 May damage fertility or the unborn child

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P318 IF exposed or concerned, get medical advice.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local regulations.

Which trade and regulatory codes apply to Trimethylolpropane?

HS Code 29054100
Storage Class 11 - Combustible Solids
WGK (Germany) 1
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