Trimethyl phosphate

CAS Number
512-56-1
EC Number
208-144-8
Abbreviation
TMP

What is Trimethyl phosphate?

Trimethyl phosphate (CAS 512-56-1), also known as TMP and trimethyl orthophosphate, is an organophosphate ester used industrially as a flame retardant additive and pH buffering agent.

Where is Trimethyl phosphate used?

  • Plastics and polymers: flame retardant plasticizer
  • Resins and coatings: incorporated to meet fire performance specifications
  • Textiles: finishing agent where controlled phosphate release contributes to flame resistance
  • Home care and industrial cleaning: pH buffer and sequestrant that stabilizes active ingredients across varying water hardness
  • Leather and paper processing: applied where controlled acidity and surface treatment consistency are required
  • Its low volatility and thermal stability make it a practical processing aid in polymer, textile and cleaning formulations.

Good to know: Buyers sourcing for specialty polymer or electronics applications should confirm specification sheets against process-specific purity requirements.

Commercial specifications

  • Purity typically 99% or higher for industrial applications
  • Clear liquid in drum and IBC quantities, with bulk tanker options for larger volumes

Other Names (Synonyms)

Trimethyl orthophosphate|Phosphoric acid, trimethyl ester|TMPO|Trimethoxyphosphine oxide|O,O,O-Trimethyl phosphate|Methyl phosphate, (MeO)3PO|PHOSPHATED DISTARCH PHOSPHATE|TMP

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What are the physical properties of Trimethyl phosphate?

Melting Point -46 °C
Boiling Point 85 °C @ Press: 26 Torr
Density 1.2144 g/cm³ @ Temp: 20 °C
Flash Point 107 °C
Appearance Clear liquid
Color Clear
Form Liquid
Water Solubility 500 G/L (25 ºC)
Vapor Pressure 1.133 hPa (25 °C)
Refractive Index n 20/D 1.395(lit.)
Log P -0.46 at 25℃

How is Trimethyl phosphate classified and handled safely? Learn More

Danger
GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H302 Harmful if swallowed
H315 Causes skin irritation
H319 Causes serious eye irritation
H320 Causes eye irritation

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.

Which trade and regulatory codes apply to Trimethyl phosphate?

HS Code 29199000
Storage Class 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
WGK (Germany) 1
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