2,2,4-Trimethyl-1,3-pentanediol

CAS Number
144-19-4
EC Number
205-619-1
Abbreviation
TMPD

What is 2,2,4-Trimethyl-1,3-pentanediol?

2,2,4-Trimethyl-1,3-pentanediol (CAS 144-19-4), commonly known as TMPD, is a specialty diol used across coatings, adhesives, and polymer systems.

Where is 2,2,4-Trimethyl-1,3-pentanediol used?

  • Coatings: coalescing solvent, plasticizer, and rheology modifier
  • Waterborne architectural and industrial coatings: coalescing agent that improves film formation
  • Adhesives and sealants: flexibility and substrate adhesion in polyurethane and acrylic formulations
  • Polyester resin synthesis: diol monomer that introduces branching to control hardness and flexibility
  • Cleaning products: carrier solvent where low volatility is required
  • It provides good solvency for organic soils in hard-surface and industrial cleaning concentrates.

Good to know: It performs well at low temperatures without the regulatory burden of conventional glycol ethers.

Commercial specifications

  • Purity typically 98% or higher
  • Packaging from drums to bulk isotanks

Other Names (Synonyms)

2,2,4-Trimethylpentane-1,3-diol|1,3-Pentanediol, 2,2,4-trimethyl-|TMPD (alcohol)|Trimethyl-1,3-Pentanediol|Caswell No. 893|Nexcoat 795|UCAR FILMER IBT|TMPD

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What are the physical properties of 2,2,4-Trimethyl-1,3-pentanediol?

Melting Point 51-52 °C
Boiling Point 234 °C @ Press: 737 Torr
Density 0.937 g/cm³ @ Temp: 15 °C
Flash Point >230 °F
Appearance (96% pure): White solid. Slightly soluble in water; soluble in alcohol, acetone, ether, and benzene. Combustible.
Color Off-White
Form Solid
Water Solubility 31.5g/L at 20℃
Vapor Pressure 0.314Pa at 20℃
Refractive Index 1.4513
Log P 1.25 at 22℃

How is 2,2,4-Trimethyl-1,3-pentanediol classified and handled safely? Learn More

Warning
GHS07· Irritant

Hazard Statements

H302 Harmful if swallowed
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.

Which trade and regulatory codes apply to 2,2,4-Trimethyl-1,3-pentanediol?

HS Code 2905.39.9000
Storage Class 11 - Combustible Solids
WGK (Germany) 1
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