Trimethyl borate

CAS Number
121-43-7
EC Number
204-468-9
Chemical Formula
C3H9BO3
Molecular Weight
103.92 g/mol
Abbreviation
TMB

Description

Trimethyl borate (CAS 121-43-7), also referred to as TMB, is a boron-containing ester used as a reactive intermediate and functional additive across chemical manufacturing. It acts as a boron source in synthesis and a flame retardant precursor. The compound also serves as a stabilizing agent in polymer and agrochemical formulations. In agrochemical production, TMB serves as a boron donor in the synthesis of active ingredients and micronutrient formulations targeting boron-deficient crops.

Polymer and plastics manufacturers incorporate it as a flame retardant additive and thermal stabilizer. This is particularly useful in coatings and resin systems where controlled boron delivery is required for performance. The pharmaceutical and fine chemical sectors use TMB as a reagent in borylation reactions and as a precursor to boronic acid derivatives. These applications require high precision and consistent chemical properties.

In textile and paper processing, it functions as a biocidal and pH-buffering agent applied during treatment baths and finishing stages. This versatility makes it a staple in diverse industrial processing environments. Trimethyl borate is supplied as a colorless liquid, typically in drum and IBC packaging suited for industrial volumes. Standard commercial grades include technical and reagent-grade specifications for various needs.

Purity levels commonly range from 97% to 99%+, meeting rigorous industrial requirements. Buyers should confirm moisture sensitivity requirements with suppliers, as grade selection affects handling and storage conditions.

Other Names (Synonyms)

boric acid, trimethyl ester|B(OMe)3|B(OCH3)3|(MeO)3B|Methyl borate|Borester O|Boric acid (H3BO3), trimethyl ester|Methyl borate ((MeO)3B)|TMB

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point -29.3 °C
Boiling Point 67-68 °C
Density 0.915 g/cm³
Flash Point 8 °F
Appearance Water-white liquid. Miscible with ether, methanol, hexane, tetrahydrofuran; decomposes in presence of water.
Color Colorless
Form Liquid
Water Solubility reacts
Vapor Pressure 147.9-148 hPa ( 20 °C)
Refractive Index n 20/D 1.358(lit.)

Documentation

Safety & Handling Learn More

Danger
GHS02· Flammable GHS07· Irritant GHS08· Health Hazard GHS06· Toxic

Hazard Statements

H225 Highly Flammable liquid and vapor
H226 Flammable liquid and vapor
H301 Toxic if swallowed
H302 Harmful if swallowed

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.

Trade & Regulatory

HS Code 29209085
UN Number 2416
ADR Class 3
Packing Group II
WGK (Germany) 3
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