3,5,5-Trimethylhexanoyl peroxide

CAS Number
3851-87-4
EC Number
223-356-0

What is 3,5,5-Trimethylhexanoyl peroxide?

3,5,5-Trimethylhexanoyl peroxide (CAS 3851-87-4), also supplied commercially as Di-(3,5,5-trimethylhexanoyl) peroxide, is an organic peroxide used as a free-radical initiator and curing agent in polymer and rubber manufacturing.

Where is 3,5,5-Trimethylhexanoyl peroxide used?

  • Plastics: free-radical polymerization of vinyl monomers, including PVC, polystyrene and acrylics
  • Rubber: cross-linking agent for targeted vulcanization profiles, particularly in EPDM and silicone elastomers
  • Coatings: radical-initiated cure of resin formulations where thermal activation is preferred over photoinitiators
  • Adhesives and sealants: cure of acrylic and peroxide-curable systems requiring defined pot life and throughput temperatures
  • Its controlled decomposition profile suits low-to-moderate temperature polymerization where precise initiation is required.

Good to know: Classified as an organic peroxide; buyers should confirm defined storage requirements with their supplier to ensure product stability.

Commercial specifications

  • 75% active concentration in a diluent
  • Temperature-controlled packaging

Other Names (Synonyms)

Peroxide, bis(3,5,5-trimethyl-1-oxohexyl)|3,5,5-trimethylhexanoyl 3,5,5-trimethylhexaneperoxoate|Di-(3,5,5-trimethylhexanoyl) peroxide

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What are the physical properties of 3,5,5-Trimethylhexanoyl peroxide?

Boiling Point 359.5±25.0 °C(Predicted)
Density 0.942±0.06 g/cm3(Predicted)
Water Solubility 10mg/L at 5℃
Vapor Pressure 0.001Pa at 25℃
Log P 3.34

How is 3,5,5-Trimethylhexanoyl peroxide classified and handled safely? Learn More

Danger
GHS02· Flammable GHS07· Irritant GHS08· Health Hazard
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