SoleChem

tert-Butyl 3,5,5-trimethylperoxyhexanoate

CAS
13122-18-4
EC
236-050-7
Mol. Weight
230.34 g/mol

Description

tert-Butyl 3,5,5-trimethylperoxyhexanoate (CAS 13122-18-4), also known commercially as tert-butyl per-iso-nonanoate, is an organic peroxide used as a free-radical source in polymer manufacturing. It functions as a polymerization initiator and curing agent across rubber, plastics, and coating applications.

In plastics and polymer production, it initiates free-radical polymerization of vinyl and acrylic monomers, controlling molecular weight and conversion rates at mid-range processing temperatures. Rubber compounders use it to cross-link elastomers.

This chemical improves mechanical strength and heat resistance in finished seals, gaskets, and molded components. In coatings and adhesive formulations, it drives the cure of unsaturated resins, enabling controlled hardening profiles suited to industrial application windows.

Sealant and elastomer producers select it where a defined half-life temperature aligns with their processing or oven-cure conditions. This ensures consistent performance during the manufacturing of high-performance industrial materials.

The product is supplied as a liquid, typically in diluted or phlegmatized form to meet transport and handling requirements for organic peroxides. Concentrations vary by supplier, with technical-grade solutions being the standard commercial offering.

Packaging ranges from small drums to bulk quantities depending on volume requirements and regional regulatory classifications. Proper storage and temperature control are essential to maintain the stability and efficacy of this reactive chemical intermediate.

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Physical Properties

Melting Point 160 °C (decomp)
Boiling Point 312.34°C (rough estimate)
Density 0.897
Appearance clear liquid
Water Solubility partly miscible
Vapor Pressure 3Pa at 30.05℃
Refractive Index 1.4295-1.4315
Log P 4.4 at 25℃

Safety & Handling (Learn More)

Danger GHS02 GHS07 GHS09
Hazard Statements
H242 Heating may cause a fire
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
H411 Toxic to aquatic life with long lasting effects
H412 Harmful to aquatic life with long lasting effects
Precautionary Statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P234 Keep only in original packaging.
P235 Keep cool.
P240 Ground and bond container and receiving equipment.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P321 Specific treatment (see … on this label).
P391 Collect spillage.
P403 Store in a well-ventilated place.
P410 Protect from sunlight.
P411 Store at temperatures not exceeding … °C/…°F.
P420 Store away from other materials.
P501 Dispose of contents/container in accordance with local regulations.
P302+P352 IF ON SKIN: Wash with plenty of water.
P332+P317 Get emergency medical help.
P333+P317 Get emergency medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.
P370+P378 Use … for extinction.

Trade & Regulatory

HS Code 29159000
UN Number 2104

Documentation

Other Names

tert-butyl 3,5,5-trimethylhexanoylperoxide|Tert butyl per-iso-nonanoate|tert-butyl 3,5,5-trimethylhexaneperoxoate|tert-butyl peroxy-3,5,5-trimethylhexanoate

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