tert-butyl peroxyacetate

CAS Number
107-71-1
EC Number
203-514-5

What is tert-butyl peroxyacetate?

Tert-butyl peroxyacetate (CAS 107-71-1), also known as tert-butyl peracetate and sold under the trade name Lupersol 70, is an organic peroxide used as a free-radical source in polymer manufacturing.

Where is tert-butyl peroxyacetate used?

  • Plastics and polymer production: initiates free-radical polymerization of vinyl monomers including styrene, acrylates, and vinyl acetate, enabling molecular weight control
  • Rubber and tire manufacturing: cross-linking agent to cure elastomers, improving mechanical strength and heat resistance
  • Co-initiator in high-temperature polymerization systems where precise radical flux is required
  • Formulators working with polyethylene and specialty resins select it for grafting reactions where other peroxides would decompose too rapidly.

Commercial specifications

  • Liquid solution, typically 75% active concentration in a diluent to reduce handling hazards
  • Supply governed by peroxide-specific transport and storage regulations
  • Packaging ranges from small drums to IBC containers

Other Names (Synonyms)

tert-Butyl peracetate|t-Butyl peracetate|Lupersol 70|t-Butyl peroxyacetate|Trigonox F-C50|ETHANEPEROXOIC ACID, 1,1-DIMETHYLETHYL ESTER|Peroxyacetic acid, tert-butyl ester|FJ3F3S50CS

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What are the physical properties of tert-butyl peroxyacetate?

Melting Point -20 °C
Boiling Point 1.405 °C @ Press: 20 Torr
Density 0.9415 g/cm³ @ Temp: 20 °C
Flash Point 99 °F
Appearance clear solution
Color Clear
Form Solution
Water Solubility 3.878g/L at 25℃
Vapor Pressure 1.966Pa at 25℃
Refractive Index n 20/D 1.412
Log P 1.6 at 25℃

How is tert-butyl peroxyacetate classified and handled safely? Learn More

Danger
GHS02· Flammable GHS06· Toxic GHS07· Irritant GHS09· Environmental Hazard GHS01· Explosive

Hazard Statements

H201 (Deleted) Explosive; mass explosion hazard [Danger Explosives]
H240 Heating may cause an explosion [Danger Self-reactive substances and mixtures; Organic peroxides]
H319 Causes serious eye irritation [Warning Serious eye damage/eye irritation]
H331 Toxic if inhaled [Danger Acute toxicity, inhalation]
H335 May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

Which trade and regulatory codes apply to tert-butyl peroxyacetate?

HS Code 29159000
UN Number 3103
ADR Class 5.2
Storage Class 5.2 - Organic peroxides and self-reacting hazardous materials
WGK (Germany) 2
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