1,1-Di(tert-butylperoxy)cyclohexane

CAS Number
3006-86-8
EC Number
221-111-2

What is 1,1-Di(tert-butylperoxy)cyclohexane?

1,1-Di(tert-butylperoxy)cyclohexane (CAS 3006-86-8), commercially known as Perkadox 16, initiates free-radical reactions that drive polymer crosslinking and addition polymerization.

Where is 1,1-Di(tert-butylperoxy)cyclohexane used?

  • Rubber compounding: crosslinks EPDM, silicone, and natural rubber for vulcanizates with improved heat resistance and compression set
  • Unsaturated polyester and acrylic resins: high-temperature cure initiator for controlled exotherm and through-cure
  • Wire and cable insulation: initiates peroxide crosslinking of polyethylene
  • Adhesive and sealant formulators incorporate it into systems that require elevated-temperature activation and durable bond strength under thermal cycling.

Good to know: It belongs to the dialkyl peroxide class and is selected for its mid-range decomposition temperature, which suits a broad range of processing conditions across rubber and plastics manufacturing.

Commercial specifications

  • Liquid concentrate, typically 50% active content on an inert carrier
  • Technical grade; purity and active oxygen content specified per batch documentation
  • Packaging: drums to intermediate bulk containers

Other Names (Synonyms)

Perkadox gb-50x|1,1-bis(tert-butylperoxy)cyclohexane

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What are the physical properties of 1,1-Di(tert-butylperoxy)cyclohexane?

Melting Point 65 °C (SADT)
Boiling Point 55 °C @ Press: 0.01 Torr
Density 0.941 g/cm³ @ Temp: 20 °C
Flash Point 155 °F
Appearance clear liquid
Color Clear
Form Liquid
Water Solubility miscible
Vapor Pressure 4.88hPa at 25℃
Refractive Index n 20/D 1.435
Log P 7.2 at 25℃

How is 1,1-Di(tert-butylperoxy)cyclohexane classified and handled safely? Learn More

Danger
GHS02· Flammable GHS07· Irritant GHS01· Explosive

Hazard Statements

H227 H227
H241 H241
H242 H242
H315 H315

Precautionary Statements

P210 P210
P234 P234
P235 P235
P240 P240

Which trade and regulatory codes apply to 1,1-Di(tert-butylperoxy)cyclohexane?

HS Code 29096000
UN Number 3103
ADR Class 5.2
Storage Class 4.1A - Other explosive hazardous materials
WGK (Germany) 2
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