SoleChem

Cumene hydroperoxide

Oxidizers & Peroxides Rubber & Tire
CAS
80-15-9
EC
201-254-7
Mol. Weight
152.19 g/mol

Description

Cumene hydroperoxide (CAS 80-15-9), also known as CHP or isopropylbenzene hydroperoxide, is an organic peroxide used industrially as a free-radical source for initiating polymerization and curing reactions.

It functions as a highly effective oxidizing agent in rubber and polymer manufacturing, where controlled radical generation is critical to process consistency. In rubber compounding, CHP acts as a cross-linking agent.

This chemical is used to vulcanize silicone and specialty elastomers, producing materials with improved heat resistance and mechanical performance. Polymer producers use it to initiate emulsion and solution polymerization.

It is effective for styrene, acrylates, and other vinyl monomers in the manufacture of resins and synthetic rubbers. It also serves as a co-agent in redox initiator systems where it pairs with reducing agents.

This enables low-temperature polymerization, which is a requirement in cold rubber processes. Tire manufacturers rely on CHP-based curing systems to achieve consistent crosslink density in high-performance rubber compounds.

Cumene hydroperoxide is supplied as a liquid, typically as an 80% or 88% active solution in cumene. Technical grade is the standard commercial specification for industrial polymerization and curing applications.

Bulk liquid supply in drums and IBC containers is the norm, with concentration and purity confirmed by titration or GC analysis per buyer specification to ensure high quality standards.

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Physical Properties

Melting Point -10 °C
Boiling Point 53 °C @ Press: 0.098 Torr
Density 1.0619 g/cm³ @ Temp: 20 °C
Flash Point 192 °C
Appearance Cumene hydroperoxide, an organic peroxide, is a colorless to pale yellow to green liquid. Mild odor.
Color Colorless to Almost colorless
Form clear liquid
Water Solubility Slightly soluble
Vapor Pressure <0.03 mm Hg ( 20 °C)
Refractive Index n 20/D 1.5230
pH >5 (20°C, 13g/L in H2O)
Log P 1.6 at 25℃

Safety & Handling (Learn More)

Danger GHS02 GHS05 GHS06 GHS08 GHS09 GHS07
Hazard Statements
H227 Combustible liquid
H242 Heating may cause a fire
H302 Harmful if swallowed
H311 Toxic in contact with skin
H312 Harmful in contact with skin
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H330 Fatal if inhaled
H331 Toxic if inhaled
H332 Harmful if inhaled
H335 May cause respiratory irritation
H341 Suspected of causing genetic defects
H371 May cause damage to organs
H372 Causes damage to organs through prolonged or repeated exposure
H373 May causes damage to organs through prolonged or repeated exposure
H401 Toxic to aquatic life
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements
P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P234 Keep only in original packaging.
P235 Keep cool.
P240 Ground and bond container and receiving equipment.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 In case of inadequate ventilation wear respiratory protection.
P316 Get emergency medical help immediately.
P317 Get emergency medical help.
P318 IF exposed or concerned, get medical advice.
P319 Get medical advice/attention if you feel unwell.
P320 Specific treatment is urgent (see … on this label).
P321 Specific treatment (see … on this label).
P330 Rinse mouth.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P403 Store in a well-ventilated place.
P405 Store locked up.
P410 Protect from sunlight.
P411 Store at temperatures not exceeding … °C/…°F.
P420 Store away from other materials.
P501 Dispose of contents/container in accordance with local regulations.
P264+P265 Wash … thoroughly after handling.
P301+P317 Get emergency medical help.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P308+P316 Get emergency medical help immediately.
P333+P317 Get emergency medical help.
P361+P364 Take off immediately all contaminated clothing and wash it before reuse.
P362+P364 Take off contaminated clothing and wash it before reuse.
P370+P378 Use … for extinction.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P301+P330+P331 Rinse mouth. Do NOT induce vomiting.
P302+P361+P354 IF ON SKIN: Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P354+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code 29096000
UN Number 3109
ADR Class 5.2
Storage Class 5.2 - Organic peroxides and self-reacting hazardous materials
WGK (Germany) 3

Documentation

Other Names

Isopropylbenzene hydroperoxide|Cumyl hydroperoxide|Cumenyl hydroperoxide|alpha,alpha-Dimethylbenzyl hydroperoxide|alpha-Cumyl hydroperoxide|alpha-Cumene hydroperoxide|7-Cumyl hydroperoxide|1-Methyl-1-phenylethyl hydroperoxide|CHP

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