Cumene hydroperoxide

CAS Number
80-15-9
EC Number
201-254-7
Chemical Formula
C9H12O2
Molecular Weight
152.19 g/mol
Abbreviation
CHP

Description

Cumene hydroperoxide (CAS 80-15-9), also known as CHP or isopropylbenzene hydroperoxide, is an organic peroxide used industrially as a free-radical source for initiating polymerization and curing reactions. It functions as a highly effective oxidizing agent in rubber and polymer manufacturing, where controlled radical generation is critical to process consistency. In rubber compounding, CHP acts as a cross-linking agent.

This chemical is used to vulcanize silicone and specialty elastomers, producing materials with improved heat resistance and mechanical performance. Polymer producers use it to initiate emulsion and solution polymerization. It is effective for styrene, acrylates, and other vinyl monomers in the manufacture of resins and synthetic rubbers. It also serves as a co-agent in redox initiator systems where it pairs with reducing agents.

This enables low-temperature polymerization, which is a requirement in cold rubber processes. Tire manufacturers rely on CHP-based curing systems to achieve consistent crosslink density in high-performance rubber compounds. Cumene hydroperoxide is supplied as a liquid, typically as an 80% or 88% active solution in cumene. Technical grade is the standard commercial specification for industrial polymerization and curing applications.

Bulk liquid supply in drums and IBC containers is the norm, with concentration and purity confirmed by titration or GC analysis per buyer specification to ensure high quality standards.

Other Names (Synonyms)

Isopropylbenzene hydroperoxide|Cumyl hydroperoxide|Cumenyl hydroperoxide|alpha,alpha-Dimethylbenzyl hydroperoxide|alpha-Cumyl hydroperoxide|alpha-Cumene hydroperoxide|7-Cumyl hydroperoxide|1-Methyl-1-phenylethyl hydroperoxide|CHP

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point -10 °C
Boiling Point 53 °C @ Press: 0.098 Torr
Density 1.0619 g/cm³ @ Temp: 20 °C
Flash Point 192 °C
Appearance Cumene hydroperoxide, an organic peroxide, is a colorless to pale yellow to green liquid. Mild odor.
Color Colorless to Almost colorless
Form clear liquid
Water Solubility Slightly soluble
Vapor Pressure <0.03 mm Hg ( 20 °C)
Refractive Index n 20/D 1.5230
pH >5 (20°C, 13g/L in H2O)
Log P 1.6 at 25℃

Documentation

Safety & Handling Learn More

Danger
GHS02· Flammable GHS05· Corrosive GHS06· Toxic GHS08· Health Hazard GHS09· Environmental Hazard GHS07· Irritant

Hazard Statements

H227 Combustible liquid
H242 Heating may cause a fire
H302 Harmful if swallowed
H311 Toxic in contact with skin

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P234 Keep only in original packaging.
P235 Keep cool.

Trade & Regulatory

HS Code 29096000
UN Number 3109
ADR Class 5.2
Storage Class 5.2 - Organic peroxides and self-reacting hazardous materials
WGK (Germany) 3
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