Methyl ethyl ketone peroxide

CAS Number
1338-23-4
EC Number
215-661-2

What is Methyl ethyl ketone peroxide?

Methyl ethyl ketone peroxide (CAS 1338-23-4), commonly known as MEKP, is an organic peroxide used as a free-radical initiator in polymer curing and crosslinking systems.

Where is Methyl ethyl ketone peroxide used?

  • Unsaturated polyester and vinyl ester resins: standard initiator for fiberglass-reinforced composites such as marine hulls, automotive panels and construction laminates
  • Gel coats and casting resins: polymerization initiator
  • Rubber compounding: crosslinking agent for heat resistance and mechanical performance in elastomeric profiles and molded parts
  • With cobalt-based accelerators it enables ambient-temperature cure cycles for open-mold and hand lay-up fabrication.

Good to know: A liquid solution diluted in plasticizers or inert carriers to reduce reactivity hazards during handling and transport. Buyers should confirm active oxygen percentage and dilution carrier with suppliers when qualifying for specific applications to ensure compatibility.

Commercial specifications

  • Commercial concentrations approximately 33% to 60% active oxygen content
  • Grades vary by reactivity profile for different resin systems and processing conditions

Other Names (Synonyms)

methyl ethyl ketone hydroperoxide|MEKP|MEK peroxide|ethyl methyl ketone peroxide|butan-2-one peroxide|2-butanone peroxide|Ketonox|Mepox

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What are the physical properties of Methyl ethyl ketone peroxide?

Melting Point <25 °C
Boiling Point 19 °C
Density 1.18 g/cm³
Flash Point 190 °F
Appearance MEKP, an organic peroxide, is a colorless liquid.
Form Liquid
Water Solubility 0.1-0.5 g/100 mL at 22 ºC
Vapor Pressure 0.644-73.6Pa at 25℃
Refractive Index n 20/D 1.455
Log P 0.3 at 25℃

How is Methyl ethyl ketone peroxide classified and handled safely? Learn More

Danger
GHS02· Flammable GHS05· Corrosive GHS07· Irritant GHS01· Explosive GHS06· Toxic GHS08· Health Hazard

Hazard Statements

H227 Combustible liquid
H241 Heating may cause a fire or explosion
H242 Heating may cause a fire
H302 Harmful if swallowed

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P234 Keep only in original packaging.
P235 Keep cool.

Which trade and regulatory codes apply to Methyl ethyl ketone peroxide?

UN Number 3105
ADR Class 5.2
Storage Class 5.2 - Organic peroxides and self-reacting hazardous materials
WGK (Germany) 1
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