2,5-dimethyl-2,5-di(tert-butylperoxy)hexane
Description
2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane, identified by CAS 78-63-7, is a high-temperature organic peroxide used as a free-radical initiator and cross-linking agent in polymer processing.
Its thermal stability at moderate storage temperatures makes it a preferred choice where controlled decomposition at elevated cure temperatures is required for industrial applications.
In rubber compounding, it cross-links EPDM, silicone, and natural rubber to improve heat resistance and compression set performance in seals, gaskets, and automotive components.
Polyolefin producers use it to initiate cross-linking in PE and PP, producing materials suited for wire and cable insulation, pipes, and high-performance foam products.
It also functions as a polymerization initiator in the production of specialty resins and thermoplastic elastomers where precise molecular weight control is needed for manufacturing.
In the tire industry, it supports sulfur-free cure systems where low extractables and improved aging properties are critical for long-term durability and performance standards.
Supplied as a liquid or absorbed onto an inert carrier as a diluted paste or powder blend, standard commercial concentrations include 90% active content liquid and diluted grades.
The Technical grade is the primary market specification, with purity and active oxygen content confirmed by certificate of analysis for every batch produced.
Physical Properties
| Melting Point | 80 °C |
| Boiling Point | 42 °C @ Press: 0.06 Torr |
| Density | 0.8728 g/cm³ @ Temp: 28 °C |
| Flash Point | 149 °F |
| Appearance | colourless to light yellow liquid |
| Color | Colourless |
| Form | Oil |
| Water Solubility | immiscible |
| Vapor Pressure | 0.002Pa at 20℃ |
| Refractive Index | n 20/D 1.423(lit.) |
| Log P | 7.34 at 20℃ |
Safety & Handling (Learn More)
Trade & Regulatory
| HS Code | 29012990 |
| UN Number | 3108 |
| ADR Class | 5.2 |
| WGK (Germany) | 1 |
Documentation
Other Names
Varox|Perhexa 3M40|Trigonox 101-101/45|Peroxide, 1,1′-(1,1,4,4-tetramethyl-1,4-butanediyl)bis[2-(1,1-dimethylethyl)|Peroxide, (1,1,4,4-tetramethyltetramethylene)bis[tert-butyl|Peroxide, (1,1,4,4-tetramethyl-1,4-butanediyl)bis[(1,1-dimethylethyl)
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