Maleic anhydride

CAS Number
108-31-6
EC Number
203-571-6
Chemical Formula
C4H2O3
Molecular Weight
98.06 g/mol
Abbreviation
MA

Description

Maleic anhydride (CAS 108-31-6), also known as MA, is a high-volume reactive monomer and chemical intermediate used across polymer, resin, and specialty chemical manufacturing. It functions primarily as a building block for unsaturated polyester resins, copolymers, and maleic acid derivatives, enabling cross-linking, surface modification, and functional grafting in downstream formulations.

In plastics and polymer processing, MA is grafted onto polyolefins such as polyethylene and polypropylene to improve adhesion, compatibility, and surface wettability in compounded materials. Unsaturated polyester resin producers rely on it as a core monomer for laminates, gel coats, and fiber-reinforced composites used in construction and automotive parts.

In textile and paper treatment, maleic anhydride-derived copolymers are used as sizing agents and surface modifiers to improve fiber bonding and coating adhesion. Personal care formulators use MA-based copolymers as film-forming and fixative agents in hair care products. Maleic anhydride is supplied as molten liquid for bulk industrial delivery.

It is also available as briquettes and flakes for easier handling in smaller volumes. Standard commercial grades include technical and industrial purity levels, typically at 99%+ purity. Specifications are aligned to major resin and polymer manufacturing requirements. Packaging ranges from bulk tankers and ISO containers to drums and supersacks depending on volume requirements.

Other Names (Synonyms)

toxilic anhydride|Maleic acid anhydride|Furan-2,5-dione|Dihydro-2,5-dioxofuran|cis-Butenedioic anhydride|2,5-Furanedione|2,5-Furandione|2,5-dioxofuran|MA

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 52.8 °C
Boiling Point 202.0 °C @ Press: 760 Torr
Density 1.48 g/cm³
Flash Point 218 °F
Appearance Maleic anhydride is colorless needles, white lumps, or pellets. Irritating, choking odor.
Color White
Odor Mild acrid odor.
Form powder
Water Solubility 79 g/100 mL (25 ºC)
Vapor Pressure 0.16 mm Hg ( 20 °C)
Refractive Index 1.4688 (estimate)
pH 0.8 (550g/l, H2O, 20℃)Hydrolysis
Log P -2.61 at 20℃

Documentation

Safety & Handling Learn More

Danger
GHS05· Corrosive GHS07· Irritant GHS08· Health Hazard GHS06· Toxic

Hazard Statements

H302 Harmful if swallowed
H311 Toxic in contact with skin
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction

Precautionary Statements

P233 Keep container tightly closed.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.

Trade & Regulatory

HS Code 29171400
UN Number 2215
ADR Class 8
Packing Group III
Storage Class 6.1D - Non-combustible acute toxic Cat.3 toxic hazardous materials or hazardous materials causing chronic effects
WGK (Germany) 1
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