SoleChem

Methacrylic anhydride

CAS
760-93-0
EC
212-084-8
Mol. Weight
154.16 g/mol

Description

Methacrylic anhydride (CAS 760-93-0), also known as methacryloyl anhydride, is a reactive acylating agent used to introduce methacryloyl functional groups onto hydroxyl- or amine-bearing substrates.

It enables the synthesis of polymerizable macromonomers and modified polymers across specialty chemical manufacturing. In polymer chemistry, it is used to functionalize natural and synthetic backbones.

This includes cellulose, chitosan, and polyols, creating UV-curable or thermally crosslinkable materials for coatings, hydrogels, and resins. Personal care formulators use methacrylated intermediates derived from this reagent.

These intermediates help build film-forming polymers and crosslinked networks in hair fixatives and skin-contact materials. In dental and biomedical polymer applications, it serves as a key reagent.

It is used for producing methacrylated monomers used in adhesive and matrix formulations. Specialty flavor and fragrance synthesis also draws on its acylating reactivity to produce ester intermediates.

These processes occur at both laboratory and pilot scale. The product is supplied as a liquid, typically with inhibitor added to prevent premature polymerization during storage and transport.

Technical and reagent grades are the most commonly available, with purity levels generally ranging from 94% to 99%+. Packaging options typically include drums and intermediate bulk containers.

Industrial quantities are standard, with smaller laboratory-scale packaging available from fine chemical suppliers. This ensures flexibility for various manufacturing and research requirements.

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Physical Properties

Melting Point -20°C
Boiling Point 45-47 °C @ Press: 2 Torr
Density 1.035 g/cm³
Flash Point 184 °F
Appearance liquid
Color Colorless to Light yellow to Light orange
Form clear liquid
Water Solubility 98g/L at 20℃
Vapor Pressure 90Pa at 20℃
Refractive Index n 20/D 1.453(lit.)
Log P 1.23

Safety & Handling (Learn More)

Danger GHS05 GHS06 GHS07
Hazard Statements
H302 Harmful if swallowed
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H331 Toxic if inhaled
H332 Harmful if inhaled
H335 May cause respiratory irritation
H302+H332 Harmful if swallowed or if inhaled
Precautionary Statements
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P316 Get emergency medical help immediately.
P317 Get emergency medical help.
P319 Get medical advice/attention if you feel unwell.
P321 Specific treatment (see … on this label).
P330 Rinse mouth.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local regulations.
P264+P265 Wash … thoroughly after handling.
P301+P317 Get emergency medical help.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P332+P317 Get emergency medical help.
P333+P317 Get emergency medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P305+P354+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code 29161900
UN Number 3265
ADR Class 8
Packing Group II
Storage Class 10 - Combustible liquids
WGK (Germany) 1

Documentation

Other Names

Methacrylic acid anhydride|Methacryloyl anhydride|2-Methyl-2-propenoic acid anhydride|2-Propenoic acid, 2-methyl-, anhydride|2-Propenoic acid, 2-methyl-, 1,1′-anhydride|MAAH (METHACRYLIC ANHYDRIDE)

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