Glycidyl methacrylate

CAS Number
106-91-2
EC Number
203-441-9
Chemical Formula
C7H10O3
Molecular Weight
142.15 g/mol
Abbreviation
GMA

Description

Glycidyl methacrylate (GMA, CAS 106-91-2), also known as 2,3-Epoxypropyl methacrylate, is a bifunctional reactive monomer combining an epoxide group with a methacrylate group in a single molecule. This dual reactivity allows it to participate in both free-radical polymerization and ring-opening crosslinking reactions, making it a valued building block for specialty polymer systems.

GMA is primarily used in the production of functional acrylic copolymers for powder coatings, where its epoxide groups react with carboxylic acid curatives to deliver durable, high-gloss finishes. In adhesives and reactive hot melts, it introduces crosslinkable sites that improve bond strength and chemical resistance in the cured film. Formulators use it as a compatibilizer and reactive coupling agent.

When blending immiscible polymers such as polyesters and polyolefins, it acts as a bridge. It also serves as a surface-functionalizing monomer in specialty coatings and grafting processes for textiles. This monomer is essential for packaging films where controlled surface chemistry is required. Glycidyl methacrylate is supplied as a clear liquid, typically with inhibitor added to prevent premature polymerization.

Technical and industrial grades are the standard commercial offering, with purity levels commonly at 97% or higher. Bulk liquid and drum packaging are the typical supply formats for industrial buyers.

Other Names (Synonyms)

2,3-Epoxypropyl methacrylate|Glycidol methacrylate|SY-Monomer G|Blemmer G|Acriester G|Blemmer GMA|Light Ester G|Methacrylic acid, 2,3-epoxypropyl ester|GMA

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point -52°C
Boiling Point 189 °C
Density 1.042 g/cm³
Flash Point 169 °F
Appearance clear liquid
Color Clear
Form Liquid
Water Solubility 0.5-1.0 g/100 mL at 20 ºC
Vapor Pressure 4.2hPa at 25℃
Refractive Index n 20/D 1.449(lit.)
Log P 0.96 at 25℃

Documentation

Safety & Handling Learn More

Danger
GHS05· Corrosive GHS06· Toxic GHS08· Health Hazard GHS07· Irritant

Hazard Statements

H227 Combustible liquid
H302 Harmful if swallowed
H311 Toxic in contact with skin
H312 Harmful in contact with skin

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

Trade & Regulatory

HS Code 29161490
UN Number 2810
ADR Class 6.1
Packing Group III
Storage Class 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
WGK (Germany) 2
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