Ethyl methacrylate

CAS Number
97-63-2
EC Number
202-597-5
Abbreviation
EMA

What is Ethyl methacrylate?

Ethyl methacrylate (CAS 97-63-2), commonly abbreviated as EMA, is a reactive methacrylate monomer used as a building block in polymer synthesis and as a flavoring agent in food applications.

Where is Ethyl methacrylate used?

  • Polymer manufacturing: polymerizable unit in acrylic and methacrylic resin systems
  • Coatings and sealants: incorporated into acrylic emulsions, copolymers and thermoplastic resins to modify flexibility, adhesion and film-forming characteristics
  • Cross-linking and curing systems: reactivity profile suits controlled glass transition temperature
  • Plastics compounding: comonomer improving impact resistance and processing behavior in specialty polymer blends
  • Flavor houses use EMA at food-grade purity as a character-impact compound in artificial fruit and dairy flavor compositions.

Good to know: Stabilized liquid, typically inhibited with hydroquinone monomethyl ether to prevent premature polymerization during storage and transport.

Commercial specifications

  • Purity typically 99% or higher

Other Names (Synonyms)

ethyl 2-methylprop-2-enoate|2-Propenoic acid, 2-methyl-, ethyl ester|Ethyl 2-methylacrylate|Ethyl 2-methyl-2-propenoate|Rhoplex AC-33|Ethyl 2-methacrylate|METHACRYLIC ACID, ETHYL ESTER|RCRA waste number U118|EMA

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What are the physical properties of Ethyl methacrylate?

Melting Point >-75 °C
Boiling Point 117 °C @ Press: 760 Torr
Density 0.9135 g/cm³ @ Temp: 20 °C
Flash Point 60 °F
Appearance colourless liquid with an unpleasant odour
Color Clear colorless
Odor Acrid acrylic.
Form Liquid
Water Solubility 4 g/L (20 ºC)
Vapor Pressure 15 mm Hg ( 20 °C)
Refractive Index n 20/D 1.413(lit.)
Log P 1.940

How is Ethyl methacrylate classified and handled safely? Learn More

Danger
GHS02· Flammable GHS07· Irritant

Hazard Statements

H225 Highly Flammable liquid and vapor
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H332 Harmful if inhaled
H335 May cause respiratory irritation

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof [electrical/ventilating/lighting/…] equipment.

Which trade and regulatory codes apply to Ethyl methacrylate?

HS Code 29161490
UN Number 2277
ADR Class 3
Packing Group II
Storage Class 3 - Flammable liquids
WGK (Germany) 1
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