2-ethylhexyl methacrylate

CAS Number
688-84-6
EC Number
211-708-6
Chemical Formula
C12H22O2
Molecular Weight
198.30 g/mol
Abbreviation
2-EHMA

Description

2-Ethylhexyl methacrylate (CAS 688-84-6), commonly abbreviated as 2-EHMA, is a long-chain acrylic monomer used to modify the flexibility, adhesion, and glass transition temperature of polymer systems. It functions as a reactive building block in emulsion and solution polymerization, allowing formulators to tune end-product performance without the need for post-processing plasticizers.

In coatings and printing inks, 2-EHMA is copolymerized to improve film flexibility and substrate adhesion, particularly on flexible packaging substrates used in industrial applications. Adhesive formulators incorporate it into pressure-sensitive and structural adhesive systems where low-temperature performance and tack balance are critical for high-performance bonding.

In personal care, it appears in film-forming polymer systems used in nail coatings and hair fixatives, where controlled softness and durability are required for consumer products. Plastics compounders use it as a reactive softening comonomer to reduce brittleness in acrylic-based materials without sacrificing clarity or processability during manufacturing.

2-Ethylhexyl methacrylate is supplied as a clear liquid, typically with an inhibitor such as MEHQ added for storage stability and to prevent premature polymerization during transit. Technical grade is the standard commercial offering, with purity specifications commonly at 98% or higher. Bulk supply is available in drums and IBC containers for industrial use.

Other Names (Synonyms)

2-EHMA|Methacrylic acid, 2-ethylhexyl ester|2-Ethylhexyl methacryate|2-Ethyl-1-hexyl methacrylate|2-Propenoic acid, 2-methyl-, 2-ethylhexyl ester|Methacrylate, 2-ethylisohexy|ethylhexyl methacrylate

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point -50 °C
Boiling Point 110 °C @ Press: 14 Torr
Density 0.880 g/cm³ @ Temp: 25 °C
Flash Point 198 °F
Appearance colourless liquid
Color Colorless
Odor Ester like odour
Form Liquid
Water Solubility <0.1 g/L
Vapor Pressure 0.13 hPa (20 °C)
Refractive Index n 20/D 1.438(lit.)
Log P 4.95 at 20℃

Safety & Handling (Learn More)

Warning
GHS07· Irritant GHS08· Health Hazard GHS09· Environmental Hazard

Hazard Statements

H227 Combustible liquid
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H320 Causes eye irritation
H335 May cause respiratory irritation
H361 Suspected of damaging fertility or the unborn child
H401 Toxic to aquatic life
H411 Toxic to aquatic life with long lasting effects
H412 Harmful to aquatic life with long lasting effects

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P318 IF exposed or concerned, get medical advice.
P319 Get medical advice/attention if you feel unwell.
P321 Specific treatment (see … on this label).
P391 Collect spillage.
P403 Store in a well-ventilated place.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local regulations.
P264+P265 Wash … thoroughly after handling.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P332+P317 Get emergency medical help.
P333+P317 Get emergency medical help.
P337+P317 If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.
P370+P378 Use … for extinction.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code 29161290
UN Number 3334
Storage Class 10 - Combustible liquids
WGK (Germany) 1

Documentation

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