2-hydroxypropyl methacrylate

CAS Number
923-26-2
EC Number
213-090-3

What is 2-hydroxypropyl methacrylate?

2-Hydroxypropyl methacrylate (CAS 923-26-2), also known as HPMA or propylene glycol monomethacrylate, is a reactive hydroxyl-functional monomer used to introduce pendant hydroxyl groups into acrylic polymer chains.

Where is 2-hydroxypropyl methacrylate used?

  • Coatings: reacts with isocyanate or melamine crosslinkers to produce two-component polyurethane topcoats with improved hardness and chemical resistance
  • Adhesives and sealants: hydroxyl-functional acrylic backbones that bond to metal, glass and plastic
  • UV-curable printing inks and packaging coatings: reactive diluent that reduces viscosity and contributes to cure speed and film flexibility
  • Plastics: comonomer to tailor glass transition temperature and surface functionality of acrylic resins
  • It enables controlled crosslinking and adhesion in polymer systems.

Good to know: Typically supplied in inhibited form to prevent premature polymerization during storage and transport.

Commercial specifications

  • Purity commonly 97% or higher for industrial use
  • Bulk quantities in drums and IBC totes; tank truck supply for high-volume buyers

Other Names (Synonyms)

propylene glycol monomethacrylate|methacrylic acid 2-hydroxypropyl ester|HPMA|beta-Hydroxypropyl methacrylate|2HPMA|2-Hydroxypropyl 2-methylacrylate|2-Hydroxypropyl 2-methyl-2-propenoate|2-hydroxy-n-propyl methacrylate

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What are the physical properties of 2-hydroxypropyl methacrylate?

Melting Point <25 °C
Boiling Point 57 °C @ Press: 0.5 Torr
Density 1.03
Flash Point 101 °C
Appearance Clear liquid
Refractive Index 1.447-1.449

How is 2-hydroxypropyl methacrylate classified and handled safely? Learn More

Warning
GHS07· Irritant
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