Mono-2-(methacryloyloxy)ethyl maleate

CAS Number
51978-15-5
EC Number
257-569-5

What is Mono-2-(methacryloyloxy)ethyl maleate?

Mono-2-(methacryloyloxy)ethyl maleate (CAS 51978-15-5), also known as HEMA maleate, is a bifunctional reactive monomer carrying both a methacrylate and a maleic acid half-ester group.

Where is Mono-2-(methacryloyloxy)ethyl maleate used?

  • Electronics: photoresist formulations and adhesion-promoting coatings where carboxylic acid groups improve substrate bonding to metals and inorganic surfaces
  • Printing and packaging: UV-curable inks and overprint varnishes for adhesion to low-energy substrates
  • Adhesives: structural and pressure-sensitive formulations with crosslinkable acid sites
  • Polymer modification: reactive compatibilizer grafted onto polymer chains for composite and laminate systems
  • Its dual reactivity allows participation in free-radical polymerization while introducing pendant carboxylic acid functionality into polymer backbones.

Good to know: An inhibitor is typically added to prevent premature polymerization during storage and transit. Proper storage conditions are required to maintain stability.

Commercial specifications

  • Packaging from small laboratory quantities to bulk drums

Other Names (Synonyms)

(Z)-4-[2-(2-methylprop-2-enoyloxy)ethoxy]-4-oxobut-2-enoic acid|Hema maleate|2-Hydroxyethyl methacrylate maleate

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What are the physical properties of Mono-2-(methacryloyloxy)ethyl maleate?

Boiling Point 374.3±22.0 °C(Predicted)
Density 1.217 g/mL at 25 °C(lit.)
Flash Point >230 °F
Refractive Index n 20/D 1.483(lit.)

How is Mono-2-(methacryloyloxy)ethyl maleate classified and handled safely? Learn More

Danger
GHS05· Corrosive GHS07· Irritant

Which trade and regulatory codes apply to Mono-2-(methacryloyloxy)ethyl maleate?

UN Number 3265
ADR Class 8
Packing Group III
WGK (Germany) 3
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