2-Hydroxyethyl Methacrylate

CAS Number
868-77-9
EC Number
212-782-2
Abbreviation
HEMA

What is 2-Hydroxyethyl Methacrylate?

2-Hydroxyethyl Methacrylate (CAS 868-77-9), commonly known as HEMA, is a hydroxyl-functional methacrylate monomer used to introduce reactive sites into polymer networks.

Where is 2-Hydroxyethyl Methacrylate used?

  • Coatings: reactive diluent and crosslinking co-monomer in UV- and peroxide-cured systems, improving film hardness and adhesion to metal and plastic
  • Adhesives and sealants: hydroxyl functionality supports bonding in acrylic and methacrylate systems, including composites for aerospace structures
  • Electronics: HEMA-based resins in conformal coatings and encapsulants with controlled cure profiles
  • In construction it contributes to polymer-modified mortars and structural bonding adhesives.

Good to know: An inhibitor is typically added to prevent premature polymerization during storage and transport. Technical and high-purity grades are offered depending on end-use sensitivity, particularly for electronics and optical applications.

Commercial specifications

  • Purity levels commonly at 97% or higher

Other Names (Synonyms)

2-hydroxyethyl 2-methylprop-2-enoate|HEMA

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What are the physical properties of 2-Hydroxyethyl Methacrylate?

Melting Point -12 °C
Boiling Point 205-208 °C
Density 1.034 g/cm³ @ Temp: 25 °C
Flash Point 207 °F
Appearance colourless liquid
Color Clear
Odor Ester like
Form Liquid
Water Solubility soluble
Vapor Pressure 0.01 mm Hg ( 25 °C)
Refractive Index n 20/D 1.453(lit.)
Log P 0.42 at 25℃

How is 2-Hydroxyethyl Methacrylate classified and handled safely? Learn More

Warning
GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled

Precautionary Statements

P233 Keep container tightly closed.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Which trade and regulatory codes apply to 2-Hydroxyethyl Methacrylate?

HS Code 29161490
Storage Class 10 - Combustible liquids
WGK (Germany) 1
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