Methacrylic acid

CAS Number
79-41-4
EC Number
201-204-4
Abbreviation
MAA

What is Methacrylic acid?

Methacrylic acid (CAS 79-41-4), commonly abbreviated as MAA, is a reactive monomer and organic acid used as a foundational building block in polymer synthesis.

Where is Methacrylic acid used?

  • Plastics and polymer manufacturing: copolymerized with acrylates, styrene, or vinyl monomers to produce resins with controlled adhesion, flexibility, and pH-responsive behavior
  • Coatings, adhesives, and ion-exchange materials: rely on these characteristics
  • Personal care: carbomer-type thickeners, film formers, and fixative resins in haircare and skincare
  • Specialty coatings and dispersions: MAA content determines carboxyl group density, influencing crosslink density and substrate adhesion in industrial finishes
  • Pharmaceutical and controlled-release applications use MAA copolymers to engineer enteric coatings that govern drug release profiles.
  • Precursor for esters, especially methyl methacrylate (MMA) and poly(methyl methacrylate) (PMMA).
  • Raw material for synthetic rubber.
  • Used to produce water-soluble polymers.

Good to know: Typically supplied with inhibitor added to prevent premature polymerization during storage and transport.

Formulation notes

  • In copolymers, at low levels (≤5%), improves latex stability, adhesive properties, wettability, and pigment dispersion, and also allows post-crosslinking reactions.
  • Unlike GAA, it does not form a thermal dimer over time.

Typical specification

  • Offered with a minimum purity of 99%.
  • Available in stabilized and glacial forms.
  • Sold in a grade intended for synthesis.

Regulatory status

  • Classified for transport as UN Class 8, Packing Group II.
  • KKDIK registration obligation applies when manufactured or imported at 1 tonne or more per year.

Storage, packaging and handling

  • Must be stored cold and protected from light in a well-ventilated area.
  • Requires special attention to prevent freezing because the crystallized monomer does not contain inhibitor and the solid lacks inhibitor and oxygen.

Frequently asked questions about Methacrylic acid

What is the HS code for methacrylic acid?
Methacrylic acid is classified under HS code 29161310.
Is methacrylic acid subject to Turkish chemical regulations?
Methacrylic acid is a chemical substance within the scope of the Turkish KKDIK Regulation.
What monomers can be copolymerized with methacrylic acid?
Methacrylic acid copolymers can be prepared with acrylic and methacrylic esters, acrylonitrile, maleic acid esters, vinyl acetate, vinyl chloride, vinylidene chloride, styrene, butadiene, ethylene, and other monomers.

Technical content is compiled and updated by the SoleChem product team from public technical sources; the certificate of analysis (COA) governs product-specific specifications.

Other Names (Synonyms)

methylacrylic acid|alpha-methylacrylic acid|alpha-methacrylic acid|2-Methylpropenoic acid|2-methylenepropionic acid|2-Methylacrylic acid|2-methyl-2-propenoic acid|2-methylprop-2-enoic acid|MAA

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What are the physical properties of Methacrylic acid?

Melting Point 16 °C
Boiling Point 163 °C @ Press: 760 Torr
Density 1.0153 g/cm³ @ Temp: 20 °C
Flash Point 170 °F
Appearance colourless liquid or crystals with an unpleasant odour.
Color Clear
Odor Repulsive
Form Liquid
Water Solubility 9.7 g/100 mL (20 ºC)
Vapor Pressure 1 mm Hg ( 20 °C)
Refractive Index n 20/D 1.431(lit.)
pH 2.0-2.2 (100g/l, H2O, 20℃)
Log P 0.93 at 22℃

How is Methacrylic acid classified and handled safely? Learn More

Danger
GHS05· Corrosive GHS07· Irritant GHS06· Toxic GHS08· Health Hazard

Hazard Statements

H227 Combustible liquid
H302 Harmful if swallowed
H304 May be fatal if swallowed and enters airways
H311 Toxic in contact with skin

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.

Which trade and regulatory codes apply to Methacrylic acid?

HS Code 29161300
UN Number 2531
ADR Class 8
Packing Group II
Storage Class 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
WGK (Germany) 1
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