Vinyl chloride

CAS Number
75-01-4
EC Number
200-831-0
Chemical Formula
C2H3Cl
Molecular Weight
62.50 g/mol

Description

Vinyl chloride (CAS 75-01-4), also known as vinyl chloride monomer (VCM), is the primary feedstock for polyvinyl chloride (PVC) production. It is one of the world's highest-volume thermoplastics. It functions as a reactive monomer that undergoes polymerization to form the polymer backbone used across construction, packaging, and industrial manufacturing. The dominant use is suspension and emulsion polymerization.

This process produces PVC resin, which is then compounded into rigid profiles, pipes, fittings, and window frames. Flexible PVC applications include wire insulation, flooring, and medical tubing. These applications rely on plasticized grades derived from VCM polymerization. Copolymerization with vinyl acetate or vinylidene chloride produces specialty resins used in coatings and adhesives.

These resins are also utilized in barrier packaging films. In industrial settings, VCM serves as a chemical intermediate in the synthesis of chlorinated solvents and other downstream chlorine-based compounds. Vinyl chloride monomer is supplied as a liquefied gas under pressure, typically in bulk quantities via pipeline, rail tanker, or pressurized ISO containers. It is a large-volume commodity chemical.

Traded at industrial/technical grade, purity specifications are generally at 99.9% or higher as standard for polymerization-grade supply. Procurement is handled through long-term offtake agreements. These agreements or spot contracts are established with petrochemical producers. The material requires specialized handling and storage infrastructure due to its physical properties and industrial scale.

Other Names (Synonyms)

vinyl chloride monomer|monovinyl chloride|ethylene monochloride|VCM|Ethene, chloro-|Ethylene, chloro-|Vinyl C monomer

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point -153.7 °C
Boiling Point -13.3 °C
Density 0.9106 g/cm³ @ Temp: 20 °C
Flash Point -78 °F
Appearance Vinyl chloride is a flammable gas at room temperature, and is usually encountered as a cooled liquid. The colorless liquid forms a vapor which has a pleasant, ethereal odor. The odor threshold is variously given as 260 ppm, 3,000 ppm (NJ fact sheet), 4000 ppm (NY fact sheet) in air and 3.4 ppm in water (EPA Toxicological profile). Shipped as a liquefied compressed gas.
Form powder
Water Solubility <1.1g/L(25 ºC)
Vapor Pressure 3,428 at 30 °C (quoted, Standen, 1964)
Refractive Index n 20/D 1.3700(lit.)

Documentation

Safety & Handling Learn More

Danger
GHS02· Flammable GHS08· Health Hazard GHS04· Compressed Gas GHS07· Irritant

Hazard Statements

H220 Extremely flammable gas
H280 Contains gas under pressure; may explode if heated
H315 Causes skin irritation
H320 Causes eye irritation

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P222 Do not allow contact with air.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.

Trade & Regulatory

HS Code 29032100
UN Number 1086
ADR Class 2.1
Storage Class 3 - Flammable liquids
WGK (Germany) 2
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