Vinyl chloride
Description
Vinyl chloride (CAS 75-01-4), also known as vinyl chloride monomer (VCM), is the primary feedstock for polyvinyl chloride (PVC) production. It is one of the world's highest-volume thermoplastics.
It functions as a reactive monomer that undergoes polymerization to form the polymer backbone used across construction, packaging, and industrial manufacturing. The dominant use is suspension and emulsion polymerization.
This process produces PVC resin, which is then compounded into rigid profiles, pipes, fittings, and window frames. Flexible PVC applications include wire insulation, flooring, and medical tubing.
These applications rely on plasticized grades derived from VCM polymerization. Copolymerization with vinyl acetate or vinylidene chloride produces specialty resins used in coatings and adhesives.
These resins are also utilized in barrier packaging films. In industrial settings, VCM serves as a chemical intermediate in the synthesis of chlorinated solvents and other downstream chlorine-based compounds.
Vinyl chloride monomer is supplied as a liquefied gas under pressure, typically in bulk quantities via pipeline, rail tanker, or pressurized ISO containers. It is a large-volume commodity chemical.
Traded at industrial/technical grade, purity specifications are generally at 99.9% or higher as standard for polymerization-grade supply. Procurement is handled through long-term offtake agreements.
These agreements or spot contracts are established with petrochemical producers. The material requires specialized handling and storage infrastructure due to its physical properties and industrial scale.
Physical Properties
| Melting Point | -153.7 °C |
| Boiling Point | -13.3 °C |
| Density | 0.9106 g/cm³ @ Temp: 20 °C |
| Flash Point | -78 °F |
| Appearance | Vinyl chloride is a flammable gas at room temperature, and is usually encountered as a cooled liquid. The colorless liquid forms a vapor which has a pleasant, ethereal odor. The odor threshold is variously given as 260 ppm, 3,000 ppm (NJ fact sheet), 4000 ppm (NY fact sheet) in air and 3.4 ppm in water (EPA Toxicological profile). Shipped as a liquefied compressed gas. |
| Form | powder |
| Water Solubility | <1.1g/L(25 ºC) |
| Vapor Pressure | 3,428 at 30 °C (quoted, Standen, 1964) |
| Refractive Index | n 20/D 1.3700(lit.) |
Safety & Handling (Learn More)
Trade & Regulatory
| HS Code | 29032100 |
| UN Number | 1086 |
| ADR Class | 2.1 |
| Storage Class | 3 - Flammable liquids |
| WGK (Germany) | 2 |
Documentation
Other Names
vinyl chloride monomer|monovinyl chloride|ethylene monochloride|VCM|Ethene, chloro-|Ethylene, chloro-|Vinyl C monomer
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