Vinylene carbonate

CAS Number
872-36-6
EC Number
212-825-5
Abbreviation
VC

What is Vinylene carbonate?

Vinylene carbonate (CAS 872-36-6), commonly abbreviated as VC, is a cyclic carbonate ester used primarily as an electrolyte additive and film-forming agent in lithium-ion battery manufacturing.

Where is Vinylene carbonate used?

  • Lithium-ion and lithium-polymer batteries: added to carbonate-based electrolyte formulations at 1–5% loading to suppress electrolyte decomposition at the anode surface
  • EV packs, consumer electronics and grid storage: specified to reduce irreversible capacity loss during formation cycling
  • Specialty polymer synthesis: building block for polycarbonate coatings and functional films requiring controlled crosslink density
  • Personal care: explored as a carrier solvent and plasticizing component in film-forming systems
  • At low concentrations it polymerizes on electrode surfaces to form a stable solid electrolyte interphase (SEI).

Commercial specifications

  • Battery-grade specifications typically require purity ≥99.5% and tightly controlled water content
  • Standard technical and high-purity electronic grades
  • Packaging from small R&D quantities to drum volumes for industrial electrolyte blending

Other Names (Synonyms)

1,3-Dioxol-2-one|1X0ZZF9WFV|RefChem:901949|Carbonic acid, cyclic vinylene ester|VC

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What are the physical properties of Vinylene carbonate?

Melting Point 22 °C
Boiling Point 162 °C
Density 1.355 g/cm³
Flash Point 163 °F
Appearance clear colorless to light yellow liquid
Color Colorless to pale yellow
Form Liquid
Water Solubility 11.5 g/100 mL
Vapor Pressure 3.35hPa at 25℃
Refractive Index n 20/D 1.421(lit.)
Log P -0.36 at 20℃

How is Vinylene carbonate classified and handled safely? Learn More

Danger
GHS05· Corrosive GHS06· Toxic GHS07· Irritant GHS08· Health Hazard GHS09· Environmental Hazard

Hazard Statements

H302 Harmful if swallowed
H311 Toxic in contact with skin
H315 Causes skin irritation
H317 May cause an allergic skin reaction

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.

Which trade and regulatory codes apply to Vinylene carbonate?

HS Code 29209090
UN Number 2810
Packing Group III
Storage Class 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
WGK (Germany) 3
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