SoleChem

Phthalic anhydride

CAS
85-44-9
EC
201-607-5
Mol. Weight
148.11 g/mol

Description

Phthalic anhydride (CAS 85-44-9), commonly abbreviated as PA, is a white crystalline solid produced by the catalytic oxidation of naphthalene or o-xylene. It functions as a foundational chemical intermediate.

This material supplies reactive anhydride groups for the synthesis of resins, plasticizers, dyes, and specialty esters across multiple industrial sectors. PA is the primary building block for alkyd resins.

These resins are used in architectural and industrial coatings, where it controls resin hardness, drying behavior, and film durability. In plastics processing, it reacts with alcohols to produce phthalate plasticizers.

These plasticizers modify flexibility in PVC compounds for cables, flooring, and packaging films. Unsaturated polyester resins for composites and laminates rely on PA as a key monomer for production.

It determines the crosslink density and mechanical performance of the cured material. It also serves as a precursor to phthalocyanine pigments and to synthetic musks and fragrance intermediates.

These intermediates are used in personal care formulations. Phthalic anhydride is supplied as white flakes or molten liquid, with flake form being the standard for bulk and bagged shipments.

Technical grade is the predominant commercial specification, with purity typically at 99.5% or higher. It is available in bulk tankers, bulk bags, and 25 kg bags depending on application requirements.

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Physical Properties

Melting Point 130.8 °C
Boiling Point 295 °C
Density 1.53 g/cm³
Flash Point 152 °C
Appearance Phthalic Anhydride is moderately flammable, white solid (flake) or a clear, colorless, mobile liquid (molten) Characteristic, acrid, choking odor
Color White
Odor Characteristic choking odor
Form Flaky Crystals
Water Solubility 6 g/L (20 ºC)
Vapor Pressure <0.01 mm Hg ( 20 °C)
Refractive Index 1.4500 (estimate)
pH 2 (6g/l, H2O, 20℃)
Log P 2.07 at 20℃

Safety & Handling (Learn More)

Danger GHS05 GHS07 GHS08
Hazard Statements
H302 Harmful if swallowed
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H319 Causes serious eye irritation
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
H361 Suspected of damaging fertility or the unborn child
H371 May cause damage to organs
H372 Causes damage to organs through prolonged or repeated exposure
H402 Harmful to aquatic life
Precautionary Statements
P203 Obtain, consult and follow expert instructions for use.
P233 Keep container tightly closed.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 In case of inadequate ventilation wear respiratory protection.
P317 Get emergency medical help.
P318 IF exposed or concerned, get medical advice.
P319 Get medical advice/attention if you feel unwell.
P321 Specific treatment (see … on this label).
P330 Rinse mouth.
P403 Store in a well-ventilated place.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local regulations.
P264+P265 Wash … thoroughly after handling.
P301+P317 Get emergency medical help.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P308+P316 Get emergency medical help immediately.
P332+P317 Get emergency medical help.
P333+P317 Get emergency medical help.
P337+P317 If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P342+P316 Get emergency medical help immediately.
P362+P364 Take off contaminated clothing and wash it before reuse.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P305+P354+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code 29173500
Storage Class 11 - Combustible Solids
WGK (Germany) 1

Documentation

Other Names

phthalic acid anhydride|ortho-phthalic acid anhydride|o-phthalic acid anhydride|isobenzofuran-1,3-dione|2-benzofuran-1,3-dione|1,3-phthalandione|1,3-isobenzofurandione|1,3-dioxophthalan|PA

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