Phthalic anhydride

CAS Number
85-44-9
EC Number
201-607-5
Chemical Formula
C8H4O3
Molecular Weight
148.11 g/mol
Abbreviation
PA

Description

Phthalic anhydride (CAS 85-44-9), commonly abbreviated as PA, is a white crystalline solid produced by the catalytic oxidation of naphthalene or o-xylene. It functions as a foundational chemical intermediate. This material supplies reactive anhydride groups for the synthesis of resins, plasticizers, dyes, and specialty esters across multiple industrial sectors. PA is the primary building block for alkyd resins.

These resins are used in architectural and industrial coatings, where it controls resin hardness, drying behavior, and film durability. In plastics processing, it reacts with alcohols to produce phthalate plasticizers. These plasticizers modify flexibility in PVC compounds for cables, flooring, and packaging films. Unsaturated polyester resins for composites and laminates rely on PA as a key monomer for production.

It determines the crosslink density and mechanical performance of the cured material. It also serves as a precursor to phthalocyanine pigments and to synthetic musks and fragrance intermediates. These intermediates are used in personal care formulations. Phthalic anhydride is supplied as white flakes or molten liquid, with flake form being the standard for bulk and bagged shipments.

Technical grade is the predominant commercial specification, with purity typically at 99.5% or higher. It is available in bulk tankers, bulk bags, and 25 kg bags depending on application requirements.

Other Names (Synonyms)

phthalic acid anhydride|ortho-phthalic acid anhydride|o-phthalic acid anhydride|isobenzofuran-1,3-dione|2-benzofuran-1,3-dione|1,3-phthalandione|1,3-isobenzofurandione|1,3-dioxophthalan|PA

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 130.8 °C
Boiling Point 295 °C
Density 1.53 g/cm³
Flash Point 152 °C
Appearance Phthalic Anhydride is moderately flammable, white solid (flake) or a clear, colorless, mobile liquid (molten) Characteristic, acrid, choking odor
Color White
Odor Characteristic choking odor
Form Flaky Crystals
Water Solubility 6 g/L (20 ºC)
Vapor Pressure <0.01 mm Hg ( 20 °C)
Refractive Index 1.4500 (estimate)
pH 2 (6g/l, H2O, 20℃)
Log P 2.07 at 20℃

Documentation

Safety & Handling Learn More

Danger
GHS05· Corrosive GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H302 Harmful if swallowed
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H318 Causes serious eye damage

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P233 Keep container tightly closed.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

Trade & Regulatory

HS Code 29173500
Storage Class 11 - Combustible Solids
WGK (Germany) 1
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