Hexahydrophthalic anhydride

CAS Number
85-42-7
EC Number
201-604-9
Abbreviation
HHPA

What is Hexahydrophthalic anhydride?

Hexahydrophthalic anhydride (CAS 85-42-7), abbreviated HHPA, is a cycloaliphatic anhydride used as a curing agent and reactive intermediate in epoxy and polyester systems.

Where is Hexahydrophthalic anhydride used?

  • Electrical encapsulation and casting: primary hardener for epoxy resin systems
  • Powder coatings: long pot life and controlled cure profiles
  • Alkyd and polyester resin synthesis: monomer building block for industrial and can coatings
  • Adhesives and sealants: reactive modifier that tunes flexibility and adhesion in structural bonding
  • Specialty plasticizers: reactive modifier for polymer matrices
  • Its cycloaliphatic backbone improves compatibility with PVC.

Good to know: Its saturated ring structure is preferred over aromatic anhydrides where UV stability and color retention matter. No FCC, USP, Ph. Eur., BP, EP or ACS grades are standard for this product.

Commercial specifications

  • Standard commercial grades at high purity for resin and coating applications
  • Typically handled and shipped in molten form for industrial volumes

Other Names (Synonyms)

Hexahydrophthalic acid anhydride|hexahydro-1,3-isobenzofurandione|Cyclohexane-1,2-dicarboxylic acid anhydride|3a,4,5,6,7,7a-hexahydroisobenzofuran-1,3-quinone|3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione|1,2-Cyclohexanedicarboxylic anhydride|1,2-Cyclohexanedicarboxylic acid anhydride|HHPA

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What are the physical properties of Hexahydrophthalic anhydride?

Melting Point 32 °C
Boiling Point 146 °C @ Press: 15 Torr
Density 1.18
Flash Point >230 °F
Color White to Off-White
Form Solid
Water Solubility 4.2g/L at 20℃
Vapor Pressure 0.31Pa at 25℃
Refractive Index 1.4620 (estimate)
Log P -4.14 at 20℃

How is Hexahydrophthalic anhydride classified and handled safely? Learn More

Danger
GHS05· Corrosive GHS08· Health Hazard GHS07· Irritant

Hazard Statements

H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness

Precautionary Statements

P233 Keep container tightly closed.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.

Which trade and regulatory codes apply to Hexahydrophthalic anhydride?

HS Code 29172090
Storage Class 11 - Combustible Solids
WGK (Germany) 1
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