Hexafluoroisopropyl acrylate

CAS Number
2160-89-6
EC Number
218-479-1

What is Hexafluoroisopropyl acrylate?

Hexafluoroisopropyl acrylate (CAS 2160-89-6) is a fluorinated acrylic monomer that introduces extreme hydrophobicity, chemical resistance, and low surface energy into polymer systems.

Where is Hexafluoroisopropyl acrylate used?

  • Specialty coatings, optical materials, and high-performance polymer formulations: reactive building block where standard acrylates fall short on durability
  • Electronics and photonics: UV-curable resins and optical coatings targeting low refractive index and moisture resistance
  • Aerospace and defense: films resisting fuels, solvents, and aggressive atmospheric conditions
  • Fluoropolymer synthesis: comonomer tuning surface energy and chemical resistance of specialty membranes and release coatings
  • Anti-fouling and hydrophobic surface treatments give substrates durable, low-adhesion finishes.

Commercial specifications

  • Inhibitor added to prevent premature polymerization during storage and transport
  • Purity commonly 97% upward

Other Names (Synonyms)

2,2,2-Trifluoro-1-(trifluoromethyl)ethyl acrylate|2-Propenoic acid, 2,2,2-trifluoro-1-(trifluoromethyl)ethyl ester|RefChem:786092|1,1,1,3,3,3-Hexafluoroisopropyl acrylate|Acrylic acid, 2,2,2-trifluoro-1-(trifluoromethyl)ethyl ester|Ethanol, 2,2,2-trifluoro-1-(trifluoromethyl)-, acrylate|HFIPA

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What are the physical properties of Hexafluoroisopropyl acrylate?

Boiling Point 84-85 °C @ Press: 760 Torr
Density 1.335 g/cm³ @ Temp: 20 °C
Flash Point 50 °F
Appearance clear colorless liquid
Color Colorless to Almost colorless
Form clear liquid
Water Solubility Insoluble
Vapor Pressure 1.22 psi ( 20 °C)
Refractive Index n 20/D 1.319(lit.)

How is Hexafluoroisopropyl acrylate classified and handled safely? Learn More

Danger
GHS02· Flammable GHS07· Irritant GHS09· Environmental Hazard

Hazard Statements

H225 Highly Flammable liquid and vapor
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
H411 Toxic to aquatic life with long lasting effects

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof [electrical/ventilating/lighting/…] equipment.

Which trade and regulatory codes apply to Hexafluoroisopropyl acrylate?

HS Code 29161290
UN Number 3272
ADR Class 3
Packing Group II
Storage Class 3 - Flammable liquids
WGK (Germany) 2
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