Hexafluorosilicic acid

CAS Number
16961-83-4
EC Number
N/A

What is Hexafluorosilicic acid?

Hexafluorosilicic acid (CAS 16961-83-4), also known as fluorosilicic acid, is a strong inorganic acid supplied primarily as an aqueous solution.

Where is Hexafluorosilicic acid used?

  • Municipal water treatment: most commonly used chemical for drinking water fluoridation, dosed to regulated concentration targets
  • Construction and concrete: hardens and densifies cementitious surfaces by reacting with calcium compounds, forming insoluble silicates that reduce porosity and improve wear resistance
  • Metal surface treatment: etchant and adhesion promoter for preparing substrates prior to coating or plating
  • Mining: ore processing and pH-regulating agent in leaching circuits for mineral extraction
  • It is produced as a byproduct of phosphate fertilizer manufacturing.

Good to know: Product quality is typically referenced against water treatment authority standards or regional regulatory requirements.

Commercial specifications

  • Aqueous solution at 20–25% and 23% w/w concentrations
  • Higher-concentration solutions up to approximately 35% for industrial uses

Other Names (Synonyms)

Hexafluorosilicon(2-);hydron|Fluorosilicic acid

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What are the physical properties of Hexafluorosilicic acid?

Boiling Point 115.4 °C
Density 1.22 g/mL at 25 °C
Flash Point 108-109°C
Appearance colourless liquid; often supplied as a colourless solution in water
Color Clear colorless
Form Liquid
Water Solubility Miscible with water.
Vapor Pressure 23hPa at 19.85℃
Refractive Index 1.3500

How is Hexafluorosilicic acid classified and handled safely? Learn More

Danger
GHS05· Corrosive GHS06· Toxic GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H290 May be corrosive to metals
H302 Harmful if swallowed
H311 Toxic in contact with skin
H314 Causes severe skin burns and eye damage

Precautionary Statements

P234 Keep only in original packaging.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.

Which trade and regulatory codes apply to Hexafluorosilicic acid?

HS Code 28111990
UN Number 1778
ADR Class 8
Packing Group II
Storage Class 6.1D - Non-combustible acute toxic Cat.3 toxic hazardous materials or hazardous materials causing chronic effects
WGK (Germany) 3
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