Hydrofluoric acid

CAS Number
7664-39-3
EC Number
231-634-8
Chemical Formula
FH
Molecular Weight
20.0064 g/mol
Abbreviation
HF

Description

Hydrofluoric acid (CAS 7664-39-3), also supplied as anhydrous hydrogen fluoride (HF), is an inorganic acid with exceptional ability to dissolve silica, oxides, and mineral scales that resist other acids. This property drives its use across electronics fabrication, metal surface treatment, and chemical synthesis at industrial scale. In semiconductor and flat-panel display manufacturing, HF etches silicon dioxide layers.

It cleans wafer surfaces with precision tolerances that other acids cannot achieve. Metal processing operations use it to pickle stainless steel and titanium, removing oxide scale and activating surfaces ahead of finishing. Fluorochemical synthesis relies on HF as a primary fluorinating agent in the production of refrigerants, fluoropolymers, and pharmaceutical intermediates. In mining and hydrometallurgy, it dissolves silicate gangue minerals.

The acid assists in uranium conversion processes during ore processing. Hydrofluoric acid is supplied as aqueous solution, with 40%, 49%, and 70% concentrations being the most commercially standard grades. Anhydrous hydrogen fluoride is available for industrial fluorination processes where water content must be minimized. Grades include technical, electronic, and reagent specifications for various industrial needs.

Electronic-grade material is subject to strict trace metal and particle limits. Our supply meets rigorous quality standards to ensure performance in high-precision manufacturing and chemical synthesis applications.

Other Names (Synonyms)

[HF]|Hydrogen fluoride|Fluorhydric acid|Rubigine|Antisal 2B|Hydrofluoricum acidum|Anhydrous hydrofluoric acid|Hydrofluoric acid gas|HF

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
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Physical Properties

Melting Point -83.36 °C
Boiling Point 20 °C
Density 0.991 g/cm³ @ Temp: 19.54 °C
Flash Point 112°C
Appearance colourless gas with a pungent odour
Color max. 10
Odor Acrid, irritating odor
Form Liquid, Double Sub-Boiling Quartz Distillation
Water Solubility soluble
Vapor Pressure 25 mm Hg ( 20 °C)
pH 3.27(1 mM solution);2.65(10 mM solution);2.12(100 mM solution)
Log P 0.1 at 20℃

Documentation

Safety & Handling Learn More

Danger
GHS05· Corrosive GHS06· Toxic GHS04· Compressed Gas GHS08· Health Hazard GHS07· Irritant

Hazard Statements

H280 Contains gas under pressure; may explode if heated
H290 May be corrosive to metals
H300 Fatal if swallowed
H310 Fatal in contact with skin

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P234 Keep only in original packaging.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

Trade & Regulatory

HS Code 28111100
UN Number 1790
ADR Class 8
Packing Group II
Storage Class 6.1B - Non-combustible, acute toxic Cat. 1 and 2 very toxic hazardous materials
WGK (Germany) 2
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