Tetrafluoroboric acid

CAS Number
16872-11-0
EC Number
240-898-3
Abbreviation
HBF4

What is Tetrafluoroboric acid?

Tetrafluoroboric acid (CAS 16872-11-0), commonly referenced by its formula HBF4, is a strong inorganic acid supplied primarily as an aqueous solution.

Where is Tetrafluoroboric acid used?

  • Metal finishing: primary electrolyte acid for tin and lead
  • Tin-lead alloy plating baths: maintains bath stability and deposit quality
  • Electronics: PCB surface treatment and flux formulations to prepare metal surfaces
  • Catalyst in polymer and resin production: promotes condensation and cyclization reactions where conventional mineral acids are unsuitable
  • Mining and metals processing: pickling and etching to selectively remove oxides from reactive metal surfaces
  • It functions as a catalyst and electrolyte component.

Commercial specifications

  • 48–50% concentration is the most commercially standard grade
  • Technical grade is the predominant specification at industrial scale
  • High-purity electronic grade for semiconductor and precision plating applications
  • Bulk supply in drums and IBC containers; smaller packaging for laboratory and specialty use

Other Names (Synonyms)

hydrogen tetrafluoroborate(1-)|hydrogen tetrafluoroborate|HBF4|fluoboric acid|borofluoric acid|fluoroboric acid|Hydrofluoboric acid

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What are the physical properties of Tetrafluoroboric acid?

Melting Point -90°C
Boiling Point 130°C (dec.)
Density ~1.84 g/cm³ (approx)
Flash Point −40 °F
Appearance Fluoboric acid is a colorless liquid which does not exist as a free, pure substance. Used as an aqueous solution.
Color Light Yellow
Odor Odorless
Form Liquid
Water Solubility MISCIBLE
Vapor Pressure 5 mmHg ( 20 °C)
Refractive Index nD20 of a 20% aq soln 1.3284

How is Tetrafluoroboric acid classified and handled safely? Learn More

Danger
GHS05· Corrosive GHS06· Toxic GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H290 May be corrosive to metals
H301 Toxic if swallowed
H311 Toxic in contact with skin
H314 Causes severe skin burns and eye damage

Precautionary Statements

P234 Keep only in original packaging.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.

Which trade and regulatory codes apply to Tetrafluoroboric acid?

HS Code 28111990
UN Number 1775
ADR Class 8
Packing Group II
Storage Class 8B - Non-combustible corrosive hazardous materials
WGK (Germany) 1
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