Tetrafluoroboric acid

CAS Number
16872-11-0
EC Number
240-898-3
Chemical Formula
BF4.H
Molecular Weight
87.82 g/mol
Abbreviation
HBF4

Description

Tetrafluoroboric acid (CAS 16872-11-0), commonly referenced by its formula HBF4, is a strong inorganic acid supplied primarily as an aqueous solution. It functions as a catalyst and electrolyte component. The material serves as a surface treatment agent across electroplating, electronics manufacturing, and specialty chemical synthesis. In metal finishing, it serves as the primary electrolyte acid for tin and lead.

It is used in tin-lead alloy plating baths, where it maintains bath stability and deposit quality. Electronics manufacturers use it in PCB surface treatment and flux formulations to prepare metal surfaces. The acid is essential for soldering and bonding processes. As a catalyst in polymer and resin production, it promotes condensation and cyclization reactions where conventional mineral acids are unsuitable.

In mining and metals processing, it is used in pickling and etching operations to selectively remove oxides from reactive metal surfaces. This ensures high-quality finishes on various industrial components. The product is supplied as an aqueous solution, with 48–50% concentration being the most commercially standard grade. Technical grade is the predominant specification available at industrial scale.

High-purity electronic grade material is offered for semiconductor and precision plating applications. Bulk supply is available in drums and IBC containers for large-scale manufacturing requirements. Smaller packaging options are also available for laboratory and specialty use. This ensures that the chemical meets the diverse needs of both research facilities and heavy industrial operations.

Other Names (Synonyms)

hydrogen tetrafluoroborate(1-)|hydrogen tetrafluoroborate|HBF4|fluoboric acid|borofluoric acid|fluoroboric acid|Hydrofluoboric acid

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point -90°C
Boiling Point 130°C (dec.)
Density ~1.84 g/cm³ (approx)
Flash Point −40 °F
Appearance Fluoboric acid is a colorless liquid which does not exist as a free, pure substance. Used as an aqueous solution.
Color Light Yellow
Odor Odorless
Form Liquid
Water Solubility MISCIBLE
Vapor Pressure 5 mmHg ( 20 °C)
Refractive Index nD20 of a 20% aq soln 1.3284

Documentation

Safety & Handling Learn More

Danger
GHS05· Corrosive GHS06· Toxic GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H290 May be corrosive to metals
H301 Toxic if swallowed
H311 Toxic in contact with skin
H314 Causes severe skin burns and eye damage

Precautionary Statements

P234 Keep only in original packaging.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.

Trade & Regulatory

HS Code 28111990
UN Number 1775
ADR Class 8
Packing Group II
Storage Class 8B - Non-combustible corrosive hazardous materials
WGK (Germany) 1
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