SoleChem

Ammonium bifluoride

CAS
1341-49-7
EC
215-676-4
Mol. Weight
57.044 g/mol

Description

Ammonium bifluoride (CAS 1341-49-7), also known as ABF, is an inorganic fluoride salt used across metal treatment, surface preparation, and industrial cleaning processes.

It delivers controlled fluoride activity in acidic conditions, making it a practical alternative to hydrofluoric acid in applications where handling pure HF is operationally difficult.

In metal processing and mining, ABF functions as a flux and etchant for removing oxide layers from aluminum, stainless steel, and other alloys prior to finishing or refining.

Electronics manufacturers use it in glass and silicon etching, where precise surface modification is required for component fabrication during the manufacturing process.

In textile and paper production, it acts as a pH buffer and flame retardant additive, contributing to fire-resistance treatments in various types of finished goods.

Building and construction applications include masonry cleaning and concrete surface treatment, where its fluoride content dissolves silicates and mineral deposits effectively.

Ammonium bifluoride is supplied as white crystalline granules or powder. Technical grade is the standard commercial form, with purity levels typically at 95–98%+.

Bulk packaging in fiber drums or HDPE containers is common for industrial supply, with smaller quantities available for laboratory or specialty use in research settings.

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Physical Properties

Melting Point 125.6 °C
Boiling Point 240 °C (decomp)
Density 1.50 g/cm³
Flash Point 238°C
Appearance white scales or flakes
Color White
Odor acidic odor
Form Solid
Water Solubility 630 g/L (20 ºC)
Vapor Pressure 1 hPa (20 °C)
pH 2 (5.7g/l, H2O, 20℃)

Safety & Handling (Learn More)

Danger GHS05 GHS06 GHS07 GHS08
Hazard Statements
H301 Toxic if swallowed
H310 Fatal in contact with skin
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H331 Toxic if inhaled
H335 May cause respiratory irritation
H370 Causes damage to organs
H371 May cause damage to organs
H372 Causes damage to organs through prolonged or repeated exposure
H373 May causes damage to organs through prolonged or repeated exposure
Precautionary Statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P316 Get emergency medical help immediately.
P317 Get emergency medical help.
P319 Get medical advice/attention if you feel unwell.
P321 Specific treatment (see … on this label).
P330 Rinse mouth.
P363 Wash contaminated clothing before reuse.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local regulations.
P264+P265 Wash … thoroughly after handling.
P301+P316 Get emergency medical help immediately.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P308+P316 Get emergency medical help immediately.
P361+P364 Take off immediately all contaminated clothing and wash it before reuse.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P301+P330+P331 Rinse mouth. Do NOT induce vomiting.
P302+P361+P354 IF ON SKIN: Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P354+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code 28261900
UN Number 1727
ADR Class 8
Packing Group II
WGK (Germany) 1

Documentation

Other Names

Ammonium difluoride|Ammonium hydrogen difluoride|Ammonium hydrofluoride|Acid ammonium fluoride|Ammonium acid fluoride|Ammonium hydrogen bifluoride|Ammonium fluoride ((NH4)(HF2))|Fluorure acide d'ammonium|ABF

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