Ammonium bifluoride

CAS Number
1341-49-7
EC Number
215-676-4
Chemical Formula
F2H.H4N
Molecular Weight
57.044 g/mol
Abbreviation
ABF

Description

Ammonium bifluoride (CAS 1341-49-7), also known as ABF, is an inorganic fluoride salt used across metal treatment, surface preparation, and industrial cleaning processes. It delivers controlled fluoride activity in acidic conditions, making it a practical alternative to hydrofluoric acid in applications where handling pure HF is operationally difficult.

In metal processing and mining, ABF functions as a flux and etchant for removing oxide layers from aluminum, stainless steel, and other alloys prior to finishing or refining. Electronics manufacturers use it in glass and silicon etching, where precise surface modification is required for component fabrication during the manufacturing process.

In textile and paper production, it acts as a pH buffer and flame retardant additive, contributing to fire-resistance treatments in various types of finished goods. Building and construction applications include masonry cleaning and concrete surface treatment, where its fluoride content dissolves silicates and mineral deposits effectively.

Ammonium bifluoride is supplied as white crystalline granules or powder. Technical grade is the standard commercial form, with purity levels typically at 95–98%+. Bulk packaging in fiber drums or HDPE containers is common for industrial supply, with smaller quantities available for laboratory or specialty use in research settings.

Other Names (Synonyms)

Ammonium difluoride|Ammonium hydrogen difluoride|Ammonium hydrofluoride|Acid ammonium fluoride|Ammonium acid fluoride|Ammonium hydrogen bifluoride|Ammonium fluoride ((NH4)(HF2))|Fluorure acide d'ammonium|ABF

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 125.6 °C
Boiling Point 240 °C (decomp)
Density 1.50 g/cm³
Flash Point 238°C
Appearance white scales or flakes
Color White
Odor acidic odor
Form Solid
Water Solubility 630 g/L (20 ºC)
Vapor Pressure 1 hPa (20 °C)
pH 2 (5.7g/l, H2O, 20℃)

Documentation

Safety & Handling Learn More

Danger
GHS05· Corrosive GHS06· Toxic GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H301 Toxic if swallowed
H310 Fatal in contact with skin
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.

Trade & Regulatory

HS Code 28261900
UN Number 1727
ADR Class 8
Packing Group II
WGK (Germany) 1
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