Ammonium bifluoride

CAS Number
1341-49-7
EC Number
215-676-4
Abbreviation
ABF

What is Ammonium bifluoride?

Ammonium bifluoride (CAS 1341-49-7), also known as ABF, is an inorganic fluoride salt.

Where is Ammonium bifluoride used?

  • Metal processing and mining: flux and etchant removing oxide layers from aluminum, stainless steel and other alloys before finishing or refining
  • Electronics: glass and silicon etching for precise surface modification in component fabrication
  • Textile and paper: pH buffer and flame retardant additive for fire-resistance treatments
  • Building and construction: masonry cleaning and concrete surface treatment, dissolving silicates and mineral deposits
  • It delivers controlled fluoride activity in acidic conditions as a practical alternative to hydrofluoric acid.

Good to know: A practical alternative to hydrofluoric acid where handling pure HF is operationally difficult.

Commercial specifications

  • Technical grade, purity typically 95–98%+
  • Bulk packaging in fiber drums or HDPE containers
  • Smaller quantities for laboratory or specialty use

Other Names (Synonyms)

Ammonium difluoride|Ammonium hydrogen difluoride|Ammonium hydrofluoride|Acid ammonium fluoride|Ammonium acid fluoride|Ammonium hydrogen bifluoride|Ammonium fluoride ((NH4)(HF2))|Fluorure acide d'ammonium|ABF

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What are the physical properties of Ammonium bifluoride?

Melting Point 125.6 °C
Boiling Point 240 °C (decomp)
Density 1.50 g/cm³
Flash Point 238°C
Appearance white scales or flakes
Color White
Odor acidic odor
Form Solid
Water Solubility 630 g/L (20 ºC)
Vapor Pressure 1 hPa (20 °C)
pH 2 (5.7g/l, H2O, 20℃)

How is Ammonium bifluoride classified and handled safely? Learn More

Danger
GHS05· Corrosive GHS06· Toxic GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H301 Toxic if swallowed
H310 Fatal in contact with skin
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.

Which trade and regulatory codes apply to Ammonium bifluoride?

HS Code 28261900
UN Number 1727
ADR Class 8
Packing Group II
WGK (Germany) 1
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