Lithium fluoride

CAS Number
7789-24-4
EC Number
232-152-0
Chemical Formula
FLi
Molecular Weight
26.0 g/mol
Abbreviation
LiF

Description

Lithium fluoride (CAS 7789-24-4), commonly abbreviated as LiF, is an inorganic salt sourced for use across metallurgical, optical, and electronics manufacturing processes. It functions as a flux agent, catalyst component, and flame retardant across a range of industrial and specialty applications. In aluminum and beryllium metallurgy, LiF is used as a flux to lower melting points and improve melt flow during smelting and casting operations. The electronics industry relies on it as a raw material for producing optical components.

These components include X-ray and UV transmission windows, where its low atomic number and wide transmission range are critical to component performance. In polymer and plastics processing, it acts as a catalyst or catalyst precursor. This occurs in specific polymerization and esterification reactions. It is also incorporated into flame retardant formulations for textiles and paper, where it contributes to char formation and combustion suppression during use.

Lithium fluoride is supplied as a white crystalline powder or fine granules. Standard commercial grades include technical grade and high-purity optical or electronic grades, with purity levels typically ranging from 98% to 99.9%+. Pharmaceutical and specialty grades meeting USP or equivalent specifications are available for controlled applications. This ensures the material meets the rigorous demands of high-tech manufacturing and chemical synthesis.

Other Names (Synonyms)

Lithium monofluoride|Lithium fluoride (LiF)|Lithium fluorure|TLD 100|NTL 50|TLD 700|1485XST65B|LiF

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
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Physical Properties

Melting Point 848 °C
Boiling Point 1681 °C
Density 2.640 g/cm³ @ Temp: 20 °C
Flash Point 1680°C
Appearance White powder
Color White to off-white
Form random crystals
Water Solubility 0.29 g/100 mL (20 ºC)
Vapor Pressure 0Pa at 25℃
Refractive Index 1.3915
pH 6.0-8.5 (25℃, 0.01M in H2O)
Log P 0.23 at 25℃

Documentation

Safety & Handling Learn More

Danger
GHS06· Toxic GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H301 Toxic if swallowed
H302 Harmful if swallowed
H315 Causes skin irritation
H319 Causes serious eye irritation

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P263 Avoid contact during pregnancy and while nursing.

Trade & Regulatory

HS Code 28261900
UN Number 3288
ADR Class 6.1
Packing Group III
Storage Class 6.1D - Non-combustible acute toxic Cat.3 toxic hazardous materials or hazardous materials causing chronic effects
WGK (Germany) 2
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