Cryolite

CAS Number
15096-52-3
EC Number
239-148-8
Chemical Formula
AlF6.3Na
Molecular Weight
209.941265 g/mol

Description

Cryolite (CAS 15096-52-3), also sold under the trade name Cryocide, is a synthetic sodium aluminum fluoride mineral used primarily as a flux and electrolyte medium in industrial processing. Commercially produced to replace the now-depleted natural mineral deposits, it is a critical input in aluminum smelting and select agrochemical and abrasive applications.

In primary aluminum production, cryolite functions as the molten bath electrolyte in Hall-Héroult cells, dissolving alumina at high temperatures to enable electrochemical reduction into metal. This functionality makes it indispensable to smelter operations. Abrasive product manufacturers incorporate it as a filler and grinding aid in resin-bonded grinding wheels and coated abrasives.

In these applications, it improves cut rate and extends wheel life. In the pulp and paper industry, it is used as an opacifying agent and filler to improve sheet brightness and printability. Historically applied as an insecticide under the Cryocide trade name, it remains a registered pesticide active ingredient in certain markets for control of chewing insects on crops.

Cryolite is supplied as a fine white powder in bulk, supersacks, and bagged formats. Technical and metallurgical grades are the most common, with purity specifications typically aligned to industry standards. Pesticide-grade material is available in select markets where regulatory approvals are maintained. Our supply chain ensures consistent quality and reliable delivery for large-scale industrial requirements.

Other Names (Synonyms)

Trisodium hexafluoroaluminate|Cryolite (Na3(AlF6))|Cryocide|Kryocide|Kryolith|ICE Spar|Cryolite (AlNa3F6)|Sodium aluminum fluoride

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 960-1027 °C
Boiling Point decomp
Density 2.95 g/cm³
Appearance Sodium aluminum fluoride is a snow-white crystalline solid, powder or vitreous mass. The crystalline solid (natural product (cryolite) may be colored reddish or brown or even black but loses this discoloration on heating); synthetic product is an amorphous powder. Odorless
Odor Odorless
Form Colorless, crystalline solid
Refractive Index 1.338

Safety & Handling (Learn More)

Danger
GHS07· Irritant GHS08· Health Hazard GHS09· Environmental Hazard

Hazard Statements

H332 Harmful if inhaled
H372 Causes damage to organs through prolonged or repeated exposure
H411 Toxic to aquatic life with long lasting effects
H412 Harmful to aquatic life with long lasting effects

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P317 Get emergency medical help.
P319 Get medical advice/attention if you feel unwell.
P391 Collect spillage.
P501 Dispose of contents/container in accordance with local regulations.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

Trade & Regulatory

HS Code 2826300000
UN Number 3077
ADR Class 9
Packing Group III
WGK (Germany) 1

Documentation

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