Cryolite

CAS Number
15096-52-3
EC Number
239-148-8

What is Cryolite?

Cryolite (CAS 15096-52-3), also sold under the trade name Cryocide, is a synthetic sodium aluminum fluoride mineral used as a flux and electrolyte medium in industrial processing.

Where is Cryolite used?

  • Aluminum smelting: molten bath electrolyte in Hall-Héroult cells, dissolving alumina at high temperatures for electrochemical reduction into metal
  • Agrochemicals: registered pesticide active ingredient for control of chewing insects on crops
  • Abrasives: filler and grinding aid in resin-bonded grinding wheels and coated abrasives
  • Pulp and paper: opacifying agent and filler that improves sheet brightness and printability
  • It is produced commercially to replace depleted natural mineral deposits.

Good to know: Pesticide-grade material is offered in select markets where regulatory approvals are maintained.

Commercial specifications

  • Fine white powder in bulk, supersacks, and bagged formats
  • Purity specifications typically aligned to industry standards

Other Names (Synonyms)

Trisodium hexafluoroaluminate|Cryolite (Na3(AlF6))|Cryocide|Kryocide|Kryolith|ICE Spar|Cryolite (AlNa3F6)|Sodium aluminum fluoride

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What are the physical properties of Cryolite?

Melting Point 960-1027 °C
Boiling Point decomp
Density 2.95 g/cm³
Appearance Sodium aluminum fluoride is a snow-white crystalline solid, powder or vitreous mass. The crystalline solid (natural product (cryolite) may be colored reddish or brown or even black but loses this discoloration on heating); synthetic product is an amorphous powder. Odorless
Odor Odorless
Form Colorless, crystalline solid
Refractive Index 1.338

How is Cryolite classified and handled safely? Learn More

Danger
GHS07· Irritant GHS08· Health Hazard GHS09· Environmental Hazard

Hazard Statements

H332 Harmful if inhaled
H372 Causes damage to organs through prolonged or repeated exposure
H411 Toxic to aquatic life with long lasting effects
H412 Harmful to aquatic life with long lasting effects

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.

Which trade and regulatory codes apply to Cryolite?

HS Code 2826300000
UN Number 3077
ADR Class 9
Packing Group III
WGK (Germany) 1
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