Trisodium hexafluoroaluminate

CAS Number
13775-53-6
EC Number
237-410-6

What is Trisodium hexafluoroaluminate?

Trisodium hexafluoroaluminate (CAS 13775-53-6), commercially known as cryolite, is a fluoride-based inorganic salt sourced from natural mineral deposits and synthesized as a synthetic equivalent.

Where is Trisodium hexafluoroaluminate used?

  • Aluminum smelting: primary flux and electrolyte medium enabling dissolution and electrochemical reduction of alumina into metallic aluminum
  • Aluminum production: molten bath in Hall-Héroult electrolytic cells, determining process efficiency and metal purity
  • Agriculture: contact insecticide under the trade name Cryocide, targeting chewing insects such as grape phylloxera and citrus pests
  • Glass and enamel: fluxing agent and opacifier that lowers melting temperatures and improves surface finish
  • It also serves as a catalyst component in certain systems.

Good to know: Synthetic cryolite is the dominant commercial form. The agricultural specification is subject to regional registration.

Commercial specifications

  • Synthetic cryolite dominant commercial form
  • Bulk supply standard for metallurgical buyers; smaller packaged quantities for agricultural and industrial use

Other Names (Synonyms)

CRYOLITE|Cryolite (Na3(AlF6))|Cryocide|Kryocide|Kryolith|ICE Spar|Cryolite (AlNa3F6)|Sodium aluminum fluoride

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What are the physical properties of Trisodium hexafluoroaluminate?

Melting Point 1009 °C
Density 1.941 g/cm³
Appearance Sodium aluminum fluoride is a snow-white crystalline solid, powder or vitreous mass. The crystalline solid (natural product (cryolite) may be colored reddish or brown or even black but loses this discoloration on heating); synthetic product is an amorphous powder. Odorless
Color White
Form Crystals
Water Solubility Sparingly soluble in water(0.602 g/L at 20°C).
Refractive Index 1.338

How is Trisodium hexafluoroaluminate classified and handled safely? Learn More

Danger
GHS07· Irritant GHS08· Health Hazard GHS09· Environmental Hazard

Hazard Statements

H332 Harmful if inhaled
H372 Causes damage to organs through prolonged or repeated exposure
H411 Toxic to aquatic life with long lasting effects
H412 Harmful to aquatic life with long lasting effects

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.

Which trade and regulatory codes apply to Trisodium hexafluoroaluminate?

UN Number 3077
ADR Class 9
Packing Group III
Storage Class 6.1D - Non-combustible acute toxic Cat.3 toxic hazardous materials or hazardous materials causing chronic effects
WGK (Germany) 1
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