Hypophosphorous acid

CAS Number
6303-21-5
EC Number
228-601-5
Abbreviation
HPA

What is Hypophosphorous acid?

Hypophosphorous acid (CAS 6303-21-5), also known as phosphinic acid and commonly abbreviated as HPA, is a reducing acid.

Where is Hypophosphorous acid used?

  • Chemical manufacturing: strong reducing agent and antioxidant that prevents oxidative degradation in sensitive formulations
  • Surface treatment: reducing agent in electroless nickel plating that drives metal deposition onto non-conductive substrates
  • Pharmaceuticals: prevents discoloration and oxidative breakdown in active ingredient formulations
  • Textile and leather processing: controls unwanted oxidation during dyeing and finishing
  • Water treatment: pH regulation and reducing agent for dissolved oxygen and metal ion activity
  • In electroless nickel plating it enables metal deposition for electronics and precision components.

Commercial specifications

  • Aqueous solution, 50% concentration most commercially standard
  • Pharmaceutical-grade material meets stricter purity requirements
  • Bulk liquid supply in IBC containers and drums

Other Names (Synonyms)

phosphinic acid|Acid, Phosphinic|RefChem:929168|8B1RL9B4ZJ|Hydroxyphosphine oxide|Phosphine oxide, hydroxy-|Phosphonous acid|HPA

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What are the physical properties of Hypophosphorous acid?

Melting Point 26.5 °C
Boiling Point 108 °C (759.8513 mmHg)
Density 1.479 g/cm³ @ Temp: 20 °C
Appearance colourless liquid
Color Colorless
Form hygroscopic crystals or colorless oily liquid
Water Solubility SOLUBLE
Vapor Pressure <17 mmHg ( 20 °C)
pH pKa1= 1.00(25℃)

How is Hypophosphorous acid classified and handled safely? Learn More

Danger
GHS05· Corrosive

Hazard Statements

H290 May be corrosive to metals
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage

Precautionary Statements

P234 Keep only in original packaging.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.

Which trade and regulatory codes apply to Hypophosphorous acid?

HS Code 28111990
UN Number 3264
ADR Class 8
Packing Group III
Storage Class 8B - Non-combustible corrosive hazardous materials
WGK (Germany) 1
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