SoleChem

Tetrakis(hydroxymethyl)phosphonium chloride

CAS
124-64-1
EC
204-707-7
Mol. Weight
190.56 g/mol

Description

Tetrakis(hydroxymethyl)phosphonium chloride (CAS 124-64-1), commonly sourced as THPC, is a reactive phosphorus-based flame retardant used across textile, leather, and industrial substrate treatments.

It functions by chemically bonding into fibrous or polymer matrices during curing, delivering durable flame retardancy rather than surface-level protection for various materials.

In textile finishing, THPC is reacted with nitrogen-containing compounds such as urea or melamine to produce wash-durable flame-retardant finishes on cotton and cellulosic fabrics.

This process is widely specified for workwear, military, and protective clothing. Leather processors apply it during wet finishing to meet fire resistance standards required in automotive upholstery.

In pulp and paper manufacturing, it functions as both a flame retardant and a cross-linking agent, improving dimensional stability in treated specialty papers and industrial products.

Building and construction applications include flame-retardant treatment of nonwoven materials and insulation substrates where regulatory compliance drives specific material requirements.

THPC is supplied as an aqueous solution, typically at 80% active content, which is the standard commercial concentration for industrial use in most manufacturing sectors.

It is available in technical grade, with supply in drums and intermediate bulk containers to suit both formulators and large-scale processors requiring consistent chemical supply.

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Physical Properties

Melting Point 154 °C
Boiling Point 115°C/760mmHg
Density 1.341 g/cm³
Appearance Clear light pink or yellow-green solution
Color Clear light pink or yellow-green
Form Solution
Water Solubility >=10 g/100 mL at 20 ºC
Vapor Pressure 0Pa at 25℃
Refractive Index n 20/D 1.512
Log P -9.8

Safety & Handling (Learn More)

Danger GHS05 GHS06 GHS07 GHS08 GHS09
Hazard Statements
H290 May be corrosive to metals
H301 Toxic if swallowed
H311 Toxic in contact with skin
H312 Harmful in contact with skin
H314 Causes severe skin burns and eye damage
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
H400 Very toxic to aquatic life
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements
P233 Keep container tightly closed.
P234 Keep only in original packaging.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 In case of inadequate ventilation wear respiratory protection.
P316 Get emergency medical help immediately.
P317 Get emergency medical help.
P321 Specific treatment (see … on this label).
P330 Rinse mouth.
P363 Wash contaminated clothing before reuse.
P390 Absorb spillage to prevent material damage.
P391 Collect spillage.
P403 Store in a well-ventilated place.
P405 Store locked up.
P406 Store in a corrosion-resistant/… container with a resistant inner liner.
P501 Dispose of contents/container in accordance with local regulations.
P264+P265 Wash … thoroughly after handling.
P301+P316 Get emergency medical help immediately.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P332+P317 Get emergency medical help.
P333+P317 Get emergency medical help.
P342+P316 Get emergency medical help immediately.
P361+P364 Take off immediately all contaminated clothing and wash it before reuse.
P362+P364 Take off contaminated clothing and wash it before reuse.
P301+P330+P331 Rinse mouth. Do NOT induce vomiting.
P302+P361+P354 IF ON SKIN: Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P354+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code 29319019
UN Number 2810
ADR Class 6.1
Packing Group III
WGK (Germany) 3

Documentation

Other Names

THPC|Pyroset TKC|TETRAMETHYLOLPHOSPHONIUM CHLORIDE|Retardol C|Phosphonium, tetrakis(hydroxymethyl)-, chloride (1:1)|NCI-C55061|Tetrakis(hydroxymethyl)phosphochloride|Tetrahydroxymethylphosphonium chloride

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