Chlorendic anhydride

CAS Number
115-27-5
EC Number
204-077-3

What is Chlorendic anhydride?

Chlorendic anhydride (CAS 115-27-5), also known as HET anhydride, is a halogenated cyclic anhydride used as a reactive flame retardant and curing agent in polymer systems.

Where is Chlorendic anhydride used?

  • Epoxy resin formulations for electrical laminates and printed circuit boards: hardener that simultaneously imparts flame retardancy, reducing the need for separate additive packages
  • Unsaturated polyester resins for construction panels, ducting, and marine components: meets fire performance standards required in building and transportation applications
  • Aerospace and defense composites: specified where structural parts must satisfy stringent self-extinguishing or low flame-spread requirements for critical safety components
  • Alkyd resin synthesis: halogen-based fire resistance built into the resin rather than applied as a coating, ensuring long-term material stability
  • Unlike additive flame retardants, it chemically incorporates into the polymer backbone, delivering durable fire resistance without migration or leaching during the product lifecycle.

Good to know: Unlike additive flame retardants, it chemically incorporates into the polymer backbone, delivering durable fire resistance without migration or leaching during the product lifecycle.

Commercial specifications

  • Technical grade, purity typically 98% or higher
  • Packaging in fiber drums or multi-wall bags suited for bulk industrial procurement
  • Store in a cool, dry environment to maintain chemical integrity

Other Names (Synonyms)

HET anhydride|1,4,5,6,7,7-Hexachloro-5-norbornene-2,3-dicarboxylic anhydride|Chloran 542|4,5,6,7,8,8-Hexachloro-3a,4,7,7a-tetrahydro-4,7-methanoisobenzofuran-1,3-dione|Chlorendic anhydride (VAN)|Hexachloro-5-norbornene-2,3-dicarboxylic anhydride|4,7-Methanoisobenzofuran-1,3-dione, 4,5,6,7,8,8-hexachloro-3a,4,7,7a-tetrahydro-

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What are the physical properties of Chlorendic anhydride?

Melting Point 239 °C
Boiling Point 486.58°C (rough estimate)
Density 173 g/cm³
Appearance WHITE CRYSTALLINE POWDER OR CHUNKS
Color White to Almost white
Form powder to crystal
Water Solubility insoluble
Vapor Pressure 0-0.003Pa at 20-24.85℃
Refractive Index 1.5550 (estimate)
Log P -1.59-1.39 at 20-25℃

How is Chlorendic anhydride classified and handled safely? Learn More

Warning
GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H335 May cause respiratory irritation

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Which trade and regulatory codes apply to Chlorendic anhydride?

HS Code 29172090
Storage Class 11 - Combustible Solids
WGK (Germany) 1
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