Methanol

CAS Number
67-56-1
EC Number
200-659-6

What is Methanol?

Methanol (CAS 67-56-1), also known as wood alcohol or wood naphtha, is a primary alcohol produced at industrial scale; used as a solvent, chemical feedstock, and fuel component.

Where is Methanol used?

  • Petrochemical and energy: blended into fuel formulations
  • Feedstock for dimethyl ether and other fuel additives
  • Pharmaceutical: process solvent for API synthesis, extraction, and chromatography-scale purification
  • Plastics and polymers: production of formaldehyde, acetic acid, and methyl methacrylate
  • Printing and packaging: solvent systems in ink formulations where fast evaporation and resin compatibility are process requirements
  • It serves as the foundational building block for downstream chemical synthesis.
  • Together with isobutylene, a raw material for the gasoline additive methyl tert-butyl ether (MTBE).
  • A coadjuvant in biodiesel production.
  • A raw material for the production of olefins, particularly ethylene, avoiding the steam cracker process from petroleum and natural gas.
  • A denaturant for ethanol.

Typical specification

  • ASTM D1152-24 is a standard specification covering methanol of 99.85% grade.
  • Soluble in water and many organic solvents.

Regulatory status

  • Classified as a highly flammable liquid and vapour under CLP hazard statement H225.
  • EU index number 603-001-00-X.
  • Classified as H331: toxic if inhaled.
  • Classified as H370: causes damage to organs.

Storage, packaging and handling

  • Poses a greater fire or explosion risk on contact with strong oxidizers.
  • Lower explosive limit (LEL) 55000 ppm.
  • Vapours are denser than air and can travel along the ground to an ignition source and cause flashback.
  • Containers can explode due to heat from a fire.

Technical content is compiled and updated by the SoleChem product team from public technical sources; the certificate of analysis (COA) governs product-specific specifications.

Other Names (Synonyms)

wood spirits|wood spirit|wood naphtha|wood alcohol|spirit of wood|pyroxylic spirit|pyroligneous spirit|Pyro alcohol

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What are the physical properties of Methanol?

Melting Point -97.8 °C
Boiling Point 64.7 °C @ Press: 760 Torr
Density 0.8100 g/cm³ @ Temp: 0 °C
Flash Point 52 °F
Appearance Methyl alcohol is a colorless, volatile liquid with a mild odor.
Color <10(APHA)
Odor Faint alcohol odor detectable at 4 to 6000 ppm (mean = 160 ppm)
Form Liquid Free From Particulates
Water Solubility miscible
Vapor Pressure 410 mm Hg ( 50 °C)
Refractive Index n 20/D 1.329(lit.)
pH 6.8 (20°C in H2O)
Log P -0.770

How is Methanol classified and handled safely? Learn More

Danger
GHS02· Flammable GHS06· Toxic GHS08· Health Hazard GHS07· Irritant

Hazard Statements

H225 Highly Flammable liquid and vapor [Danger Flammable liquids]
H301 Toxic if swallowed [Danger Acute toxicity, oral]
H311 Toxic in contact with skin [Danger Acute toxicity, dermal]
H331 Toxic if inhaled [Danger Acute toxicity, inhalation]

Which trade and regulatory codes apply to Methanol?

HS Code 29051100
UN Number 1170
ADR Class 3
Packing Group II
Storage Class 3 - Flammable liquids
WGK (Germany) 1
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