Diammonium phosphate

CAS Number
7783-28-0
EC Number
231-987-8
Abbreviation
DAP

What is Diammonium phosphate?

Diammonium phosphate (CAS 7783-28-0), commonly known as DAP, is an inorganic ammonium salt with dual function as a flame retardant and pH buffering agent. Also called secondary ammonium phosphate.

Where is Diammonium phosphate used?

  • Agriculture: concentrated phosphorus-nitrogen fertilizer applied to soil or blended into NPK compound fertilizers
  • Textile and leather: flame-retarding treatment for fabrics, paper and hides
  • Construction: fireproofing formulations for wood, insulation boards and coatings
  • Fermentation: nutrient and pH buffer in yeast-based processes such as bioethanol production and food manufacturing
  • Under heat it releases ammonia and phosphoric acid, making it effective in fire suppression.
  • Used as a flux for soldering tin, copper, zinc, and brass.
  • Main component of ABC fire extinguishers, effective against class A, B and C fires.
  • In feed it is used as a phosphorus source in mineral-supplemented compound feed production.

Formulation notes

  • Incompatible with alkaline chemicals because its ammonium ion converts to ammonia in a high-pH environment.
  • For basal application, provides full phosphorus and one-third to one-half of the nitrogen dose.
  • Fertilizer is more effective than triple superphosphate (TSP) especially in calcareous soils with pH above 7.5.
  • Should be placed below the seed and slightly to the side.

Typical specification

  • Typical fertilizer grade is 18-46-0 (18% N, 46% P2O5, 0% K2O).
  • Solubility is reported as approximately 588 g/L at 20 °C.
  • pH is 7.6–8.2 (100 g/L in water at 20 °C).
  • Offered in technical, FCC and food grades.

Regulatory status

  • Has the food additive code E342(ii) and is classified as an antioxidant.

Storage, packaging and handling

  • Has a lower critical relative humidity (below 70%) and is more hygroscopic than monoammonium phosphate (MAP).
  • Commonly packed in 50 kg bags.
  • Decomposition begins at temperatures as low as 70°C, releasing ammonia and forming monoammonium phosphate.

Frequently asked questions about Diammonium phosphate

What are the application precautions for diammonium phosphate in soil?
Placing it too close to seeds can cause seedling damage due to ammonium release and localized pH rise.
What is the optimal dosage of diammonium phosphate as a yeast nutrient?
The optimal level as a nutrient for yeast is 10-20 ppm.

Technical content is compiled and updated by the SoleChem product team from public technical sources; the certificate of analysis (COA) governs product-specific specifications.

Other Names (Synonyms)

secondary ammonium phosphate|phosphoric acid, diammonium salt|hydrogen diammonium phosphate|diammonium orthophosphate|diammonium monohydrogen phosphate|diammonium hydrogen phosphate|diammonium hydrogen orthophosphate|diammonium acid phosphate|DAP

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What are the physical properties of Diammonium phosphate?

Melting Point 155 °C (decomp)
Density 1.619 g/cm³
Appearance Ammonium phosphate is a white crystalline or powdery substance.
Color White
Odor wh. cryst. or powd., odorless, cooling salty taste
Form Powder
Water Solubility 58 g/ 100mL (10 ºC)
Vapor Pressure 0.076Pa at 20℃
pH 7.6-8.2 (100g/l, H2O, 20℃)
Log P -2.148 (est)

How is Diammonium phosphate classified and handled safely? Learn More

Warning
GHS07· Irritant

Hazard Statements

H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.

Which trade and regulatory codes apply to Diammonium phosphate?

HS Code 31053000
UN Number 3465
ADR Class 6.1
Packing Group III
WGK (Germany) 1
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