Monoammonium phosphate

CAS Number
7722-76-1
EC Number
231-764-5
E Number
E329
Abbreviation
MAP

What is Monoammonium phosphate?

Monoammonium phosphate (CAS 7722-76-1), commonly known as MAP or designated E342 in food applications, is an inorganic ammonium salt used industrially as a flame retardant and pH buffering agent.

Where is Monoammonium phosphate used?

  • Agriculture: high-analysis fertilizer applied directly to soil
  • Fertigation: dissolved to supply phosphorus and nitrogen in plant-available form
  • Textiles, paper and cellulosic materials: flame retardant that interrupts combustion at the fiber level
  • Construction: intumescent coatings and fire-retardant board treatments requiring controlled char formation
  • Leather processing and industrial manufacturing: buffer solutions and pH adjustment
  • It delivers both nitrogen and phosphorus in a single compound.
  • Component of ABC powder in some fire extinguishers.
  • Crystals are widely used in optics due to birefringence properties.
  • Nutrient source for yeasts and bacteria in fermentation.
  • Used in the preparation of DNA and RNA samples for analysis.

Formulation notes

  • For foliar application, sprayed at 100-300 g per 100 liters of water.
  • For fertigation of citrus, apply 20-25 kg/ha per week or 150-350 kg/ha total.
  • Should not be mixed with fertilizers containing calcium or magnesium.
  • Can be used together with potassium nitrate, urea, and suitable water-soluble NPK products.

Typical specification

  • NP fertilizer with a declared grade of 12% total nitrogen and 61% water-soluble P2O5 (12-61-0).
  • Offered in powder form.
  • Technical grade has a P2O5 content of minimum 60.8%.
  • Solubility of 58 g/100 ml in water at 25 °C.

Regulatory status

  • Marketed as an EC fertilizer (ABONO CE) of the NP type.
  • Agricultural, technical, feed, food, and pharmaceutical quality classes should not be used interchangeably.
  • Assigned INS number 342(i).
  • The MTDI for phosphorus from all sources is 70 mg/kg body weight, expressed as P.

Storage, packaging and handling

  • Containers should be stored between 5 and 35 °C in a dry, well-ventilated place.
  • Commonly packaged in 25 kg bags.
  • Moisture-exposed material can clump, lose flowability, have longer dissolution time, and cause bridging in dosing equipment.

Frequently asked questions about Monoammonium phosphate

What grade forms of monoammonium phosphate are available?
It is manufactured for both food and technical applications.

Technical content is compiled and updated by the SoleChem product team from public technical sources; the certificate of analysis (COA) governs product-specific specifications.

Other Names (Synonyms)

Primary ammonium phosphate|Phosphoric acid, monoammonium salt|NH4H2PO4|Monobasic ammonium phosphate|Monoammonium orthophosphate|Monoammonium hydrogen phosphate|Monoammonium dihydrogen phosphate|Monoammonium dihydrogen orthophosphate|MAP|E342

Contact us for supply of Monoammonium phosphate

Request Quote

What are the physical properties of Monoammonium phosphate?

Melting Point 190 °C
Boiling Point 376.1 °C (decomp)
Density 1.803 g/cm³
Appearance Ammonium phosphate is a white crystalline or powdery substance.
Color White or colorless
Odor brilliant wh. cryst. or powd., odorless
Form Solid
Water Solubility 368 g/L (20 ºC)
Vapor Pressure 0.066 hPa (125 °C)
Refractive Index 1.525
pH 3.8-4.4 (25℃, 50mg/mL in H2O)
Log P -2.148 (est)

How is Monoammonium phosphate classified and handled safely? Learn More

Warning
GHS07· Irritant

Hazard Statements

H319 Causes serious eye irritation

Precautionary Statements

P280 Wear protective gloves/protective clothing/eye protection/face protection.
P264+P265 Wash … thoroughly after handling.
P337+P317 If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Which trade and regulatory codes apply to Monoammonium phosphate?

HS Code 31054000
UN Number 3264
Storage Class 11 - Combustible Solids
WGK (Germany) 1
Call Request Quote