Monoammonium phosphate
What is Monoammonium phosphate?
Monoammonium phosphate (CAS 7722-76-1), commonly known as MAP or designated E342 in food applications, is an inorganic ammonium salt used industrially as a flame retardant and pH buffering agent.
Where is Monoammonium phosphate used?
- Agriculture: high-analysis fertilizer applied directly to soil
- Fertigation: dissolved to supply phosphorus and nitrogen in plant-available form
- Textiles, paper and cellulosic materials: flame retardant that interrupts combustion at the fiber level
- Construction: intumescent coatings and fire-retardant board treatments requiring controlled char formation
- Leather processing and industrial manufacturing: buffer solutions and pH adjustment
- It delivers both nitrogen and phosphorus in a single compound.
- Component of ABC powder in some fire extinguishers.
- Crystals are widely used in optics due to birefringence properties.
- Nutrient source for yeasts and bacteria in fermentation.
- Used in the preparation of DNA and RNA samples for analysis.
Formulation notes
- For foliar application, sprayed at 100-300 g per 100 liters of water.
- For fertigation of citrus, apply 20-25 kg/ha per week or 150-350 kg/ha total.
- Should not be mixed with fertilizers containing calcium or magnesium.
- Can be used together with potassium nitrate, urea, and suitable water-soluble NPK products.
Typical specification
- NP fertilizer with a declared grade of 12% total nitrogen and 61% water-soluble P2O5 (12-61-0).
- Offered in powder form.
- Technical grade has a P2O5 content of minimum 60.8%.
- Solubility of 58 g/100 ml in water at 25 °C.
Regulatory status
- Marketed as an EC fertilizer (ABONO CE) of the NP type.
- Agricultural, technical, feed, food, and pharmaceutical quality classes should not be used interchangeably.
- Assigned INS number 342(i).
- The MTDI for phosphorus from all sources is 70 mg/kg body weight, expressed as P.
Storage, packaging and handling
- Containers should be stored between 5 and 35 °C in a dry, well-ventilated place.
- Commonly packaged in 25 kg bags.
- Moisture-exposed material can clump, lose flowability, have longer dissolution time, and cause bridging in dosing equipment.
Frequently asked questions about Monoammonium phosphate
- What grade forms of monoammonium phosphate are available?
- It is manufactured for both food and technical applications.
Technical content is compiled and updated by the SoleChem product team from public technical sources; the certificate of analysis (COA) governs product-specific specifications.
Other Names (Synonyms)
Primary ammonium phosphate|Phosphoric acid, monoammonium salt|NH4H2PO4|Monobasic ammonium phosphate|Monoammonium orthophosphate|Monoammonium hydrogen phosphate|Monoammonium dihydrogen phosphate|Monoammonium dihydrogen orthophosphate|MAP|E342