Azobisisobutyronitrile

CAS Number
78-67-1
EC Number
201-132-3
Chemical Formula
C8H12N4
Molecular Weight
164.21 g/mol
Abbreviation
AIBN

Description

Azobisisobutyronitrile (CAS 78-67-1), commonly known as AIBN, is a free-radical initiator used to drive polymerization reactions across a broad range of industrial polymer production processes. It decomposes at moderate temperatures to generate nitrogen gas and carbon-centered radicals, triggering chain growth in both bulk and solution polymerization systems.

In plastics and polymer manufacturing, AIBN initiates the production of PVC, polystyrene, polyacrylates, and other vinyl-based polymers where controlled radical generation is critical. Coating formulators use it to cure acrylic and styrenic resin systems, directly influencing film hardness, adhesion, and cross-link density in the final coating application.

In adhesives and sealants, AIBN supports the synthesis of pressure-sensitive and structural adhesive polymers where consistent initiation efficiency affects batch-to-batch performance. Printing and packaging applications rely on AIBN-initiated resins for UV-stable inks and barrier coatings applied to flexible substrates for various industrial uses.

AIBN is supplied as a white crystalline powder and is the standard commercial form for industrial use. Technical grade is the predominant specification available for buyers. Purity levels are typically at 98% or higher. Packaging ranges from small quantities to bulk volumes, with temperature-controlled handling required throughout the supply chain.

Other Names (Synonyms)

AIBN|2,2'-Azobis(2-methylpropionitrile)|Azdh|Porofor N|Aceto AZIB|Pianofor an|Porofor 57|Chkhz 57

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 105 °C
Boiling Point >260 °C
Density 0.68 g/cm³ (soild)
Flash Point 4°C
Appearance Azobisisobutylonitrile is a white crystalline compound.
Color Crystals from EtOH
Odor odorless
Form Solid
Water Solubility Insoluble
Vapor Pressure 0.81Pa at 24.85℃
Refractive Index n20/D1.495
Log P 1.1 at 25℃

Documentation

Safety & Handling Learn More

Danger
GHS02· Flammable GHS07· Irritant GHS06· Toxic GHS08· Health Hazard

Hazard Statements

H242 Heating may cause a fire
H301 Toxic if swallowed
H302 Harmful if swallowed
H332 Harmful if inhaled

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P234 Keep only in original packaging.
P235 Keep cool.

Trade & Regulatory

HS Code 29269090
UN Number 3234
ADR Class 4.1
Storage Class 3 - Flammable liquids
WGK (Germany) 2
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