SoleChem

Isobutyl methacrylate

CAS
97-86-9
EC
202-613-0
Mol. Weight
142.20 g/mol

Description

Isobutyl methacrylate (CAS 97-86-9), commonly abbreviated as IBMA, is a methacrylate monomer used to build flexibility, adhesion, and hardness balance into polymer systems.

It functions as a reactive building block in emulsion, solution, and bulk polymerization processes across coatings, adhesives, and specialty resin manufacturing industries worldwide.

In architectural and industrial coatings, IBMA is copolymerized to tune film hardness and outdoor durability without sacrificing flexibility. Automotive refinish formulators incorporate it into acrylic resins.

Controlled glass transition temperature is critical to coating performance in these applications. In pressure-sensitive and structural adhesives, it contributes to tack and cohesive strength.

This occurs when the monomer is balanced against harder or softer comonomers. Printing inks and packaging lacquers use IBMA-based copolymers to achieve adhesion to difficult substrates.

These substrates often include various films and foils used in the packaging sector. Isobutyl methacrylate is supplied as a clear liquid, typically inhibited with MEHQ to prevent polymerization.

Hydroquinone monomethyl ether ensures stability during storage and transport. It is available in technical and monomer-grade specifications suited to industrial polymerization applications.

Standard packaging includes drums and ISO tank containers, with bulk quantities available for high-volume polymer producers requiring consistent material for large-scale manufacturing.

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Physical Properties

Melting Point -37 °C
Boiling Point 155 °C @ Press: 760 Torr
Density 0.8858 g/cm³ @ Temp: 20 °C
Flash Point 107 °F
Appearance colourless liquid
Color Clear colorless
Odor ether-like odor
Form Liquid
Water Solubility Soluble in water at 20°C, 2g/L
Vapor Pressure 3.5 mm Hg ( 20 °C)
Refractive Index n 20/D 1.420(lit.)
Log P 2.95 at 20℃

Safety & Handling (Learn More)

Warning GHS02 GHS07 GHS09
Hazard Statements
H226 Flammable liquid and vapor
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H320 Causes eye irritation
H335 May cause respiratory irritation
H400 Very toxic to aquatic life
H402 Harmful to aquatic life
Precautionary Statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof [electrical/ventilating/lighting/…] equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P319 Get medical advice/attention if you feel unwell.
P321 Specific treatment (see … on this label).
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local regulations.
P264+P265 Wash … thoroughly after handling.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P332+P317 Get emergency medical help.
P333+P317 Get emergency medical help.
P337+P317 If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.
P370+P378 Use … for extinction.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code 29161290
UN Number 2283
ADR Class 3
Packing Group III
WGK (Germany) 1

Documentation

Other Names

Methacrylic acid, isobutyl ester|2-Propenoic acid, 2-methyl-, 2-methylpropyl ester|Isobutyl 2-methyl-2-propenoate|2-METHYLPROPYL METHACRYLATE|Isobutyl alpha-methacrylate|Isobutyl alpha-methylacrylate|Isobutylester kyseliny methakrylove|Isobutyl α-methylacrylate|IBMA

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