Amines REACH

2-naphthylamine

CAS Number
91-59-8
EC Number
202-080-4

What is 2-naphthylamine?

2-Naphthylamine (CAS 91-59-8), also known as beta-naphthylamine, is an aromatic amine historically used as a chemical intermediate in the synthesis of dyes, rubber antioxidants, and pharmaceutical compounds.

Where is 2-naphthylamine used?

  • Dye manufacturing: precursor to azo dyes for textile and leather coloring
  • Agrochemicals: synthesis of pesticide intermediates
  • Pharmaceuticals: reactivity used to build naphthalene-based active compound scaffolds
  • Rubber processing: starting material for antioxidant production
  • In organic synthesis it serves as a building block for complex nitrogen-containing ring systems.

Good to know: Classified as a confirmed human carcinogen and subject to significant regulatory restrictions in many jurisdictions; procurement requires verification of local compliance before sourcing.

Commercial specifications

  • Technical grade is the standard commercial form for industrial buyers seeking high-purity precursors for synthesis.

Other Names (Synonyms)

beta-naphthylamine|6-naphthylamine|2-aminonaphthalene|BNA|naphthalen-2-amine|2-Naphthalenamine|beta-Naftilamina|2-Naphthalamine

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What are the physical properties of 2-naphthylamine?

Melting Point 111-113 °C
Boiling Point 306 °C
Density 1.061 g/cm³ @ Temp: 98 °C
Appearance 2-Naphthylamine is a white to red crystals with a faint, aromatic odor. Darkens in air to a reddish-purple color.
Color pink to purple
Form powder
Water Solubility <0.1 g/100 mL at 22 ºC
Vapor Pressure 2.56 x 10 -4 mmHg at 20–30 °C (quoted, Mercer et al., 1990)
Refractive Index 1.5000 (estimate)

How is 2-naphthylamine classified and handled safely? Learn More

Danger
GHS07· Irritant GHS08· Health Hazard GHS09· Environmental Hazard

Hazard Statements

H302 Harmful if swallowed
H341 Suspected of causing genetic defects
H350 May cause cancer
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
H411 Toxic to aquatic life with long lasting effects

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.

Which trade and regulatory codes apply to 2-naphthylamine?

HS Code 29214500
UN Number 1650
ADR Class 6.1
Packing Group II
WGK (Germany) 3
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