1-naphthol

CAS Number
90-15-3
EC Number
201-969-4

What is 1-naphthol?

1-Naphthol (CAS 90-15-3) is a hydroxylated naphthalene compound used primarily as a chemical intermediate. Also sold under the dye intermediate designations Zoba ERN, Ursol ERN, and Tertral ERN.

Where is 1-naphthol used?

  • Dyes and pigments: synthesis intermediate
  • Pharmaceuticals: precursor to active ingredients and antioxidant stabilizer in drug formulations
  • Textile and leather dyeing: coupling component in azo dye production
  • Printing inks and packaging coatings: key intermediate for naphthol-based pigments
  • Personal care: oxidative hair dye systems with controlled coupling reactions
  • It reacts with diazonium salts to generate deep, fast colors on fiber substrates.

Good to know: Technical grade is the standard commercial form, with purity typically at 98% or higher. Pharmaceutical-grade material meeting USP or BP specifications is available for regulated synthesis applications.

Commercial specifications

  • Purity typically 98% or higher (technical grade)

Other Names (Synonyms)

Zoba ERN|Ursol ERN|Tertral ERN|Naphthyl-1-ol|Naphthol-1|naphthalen-1-ol|Nako TRB|Furro ER

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What are the physical properties of 1-naphthol?

Melting Point 96 °C
Boiling Point 288 °C
Density 1.0954 g/cm³ @ Temp: 98.7 °C
Flash Point 125 °C
Appearance Pale grey to brown solid
Color white to off-white
Odor Slight phenolic odor
Form Crystalline Flakes
Water Solubility 436.7mg/L(25 ºC)
Vapor Pressure 1 mm Hg ( 94 °C)
Refractive Index 1.6224
Log P 2.84 at 25℃

How is 1-naphthol classified and handled safely? Learn More

Danger
GHS05· Corrosive GHS07· Irritant GHS06· Toxic GHS09· Environmental Hazard GHS08· Health Hazard

Hazard Statements

H302 Harmful if swallowed
H311 Toxic in contact with skin
H312 Harmful in contact with skin
H314 Causes severe skin burns and eye damage

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.

Which trade and regulatory codes apply to 1-naphthol?

HS Code 29071510
UN Number 2811
ADR Class 6.1
Packing Group III
WGK (Germany) 1
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